Citation: Qin Xujin, Han Jianlei, Yang Dong, Chen Wenjie, Zhao Tonghan, Jin Xue, Guo Peipei, Duan Pengfei. Chiral self-assembly regulated photon upconversion based on triplet-triplet annihilation[J]. Chinese Chemical Letters, ;2019, 30(11): 1923-1926. doi: 10.1016/j.cclet.2019.04.035 shu

Chiral self-assembly regulated photon upconversion based on triplet-triplet annihilation

Qin Xujin ^a ,
Han Jianlei ^b ,
Yang Dong ^b ,
Chen Wenjie ^b ,
Zhao Tonghan ^b ,
Jin Xue ^b ,
Guo Peipei ^a,*, ,
Duan Pengfei ^b,*,

a.
School of Chemistry and Life Science, Advanced Institute of Materials Science, Changchun University of Technology, Changchun 130012, China
b.
CAS Center for Excellence in Nanoscience, CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology(NCNST), Beijing 100190, China

guopeipei@ccut.edu.cn

duanpf@nanoctr.cn

Received Date: 17 March 2019
Revised Date: 11 April 2019
Accepted Date: 12 April 2019
Available Online: 17 November 2019

Figures(4)

Photon upconversion (UC) based on triplet-triplet annihilation (TTA) in quasi-solid or solid state has been attracting much research interest due to its great potential applications. To get effective UC, precisely controlled donor-acceptor interaction is vitally important. Chiral self-assembly provides a powerful approach for sophisticated regulation of molecular interaction. Here we report a chiral self-assembly controlled TTA-UC system composed of chiral acceptor and achiral donor. It is found that racemic mixture of acceptors could form straight fibrous nanostructures, which show strong UC emission, while chiral assemblies for homochiral acceptors emit weak upconverted light. The racemic assemblies allow efficient triplet-triplet energy transfer (TTET) and further realize efficient UC emission, while the homochiral assemblies from chiral acceptor produce twisted nanostructures, suppressing efficient triplet energy transfer and annihilation. The establishment of such chiral self-assembly controlled UC system highlights the potential applications of triplet fusion in optoelectronic materials and provides a new perspective for designing highly effective UC systems.
- Photon upconversion,
- Triplet,
- Self-assembly,
- Chirality,
- Organogel
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