Citation: Sun Shuangjiao, Guan Qingwen, Liu Yao, Wei Bin, Yang Yuanyuan, Yu Zhiqiang. Highly luminescence manganese doped carbon dots[J]. Chinese Chemical Letters, ;2019, 30(5): 1051-1054. doi: 10.1016/j.cclet.2019.01.014 shu

Highly luminescence manganese doped carbon dots

Sun Shuangjiao ^a ,
Guan Qingwen ^b ,
Liu Yao ^b,c,**, ,
Wei Bin ^b ,
Yang Yuanyuan ^d ,
Yu Zhiqiang ^d,*,

a.
School of Pharmaceutical Sciences, Shaoyang University, Shaoyang 422000, China
b.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing, Beijing 102249, China
c.
Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing 402160, China
d.
School of Pharmaceutical Sciences, Guangdong Provincial Key Laboratory of New Drug Screening, Southern Medical University, Guangzhou 510515, China

bnliuyao@163.com

yuzq@smu.edu.cn

Received Date: 24 September 2018
Revised Date: 3 January 2019
Accepted Date: 14 January 2019
Available Online: 14 May 2019

Figures(6)

Heteroatom doped carbon dots (CDs) with distinct merits are of great attractions in various fields such as solar cells, catalysis, trace element detection and photothermal therapy. In this work, we successfully synthesized blue-fluorescence and photostability manganese-doped carbon dots (Mn-CDs) with a quantum yield up to 7.5%, which was prepared by a facile one-step hydrothermal method with sodium citrate and manganese chloride. The Mn-CDs is the high mono-dispersity, uniform spherical nanoparticles. The Mn element plays a critical role in achieving a high quantum yield in synthesis of carbon dots, which was confirmed by the structure analysis using XPS and FTIR. Spectroscopic investigations proved that the decent PLQY and luminescence properties of Mn-CDs are due to the heteroatom doped, oxidized carbon-based surface passivation. In addition, the Mn-CDs are demonstrated as promising fluorescent sensors for iron ions with a linear range of 0-500 μmol/L and a detection limit of 2.1 nmol/L (turn-off), indicating their great potential as a fluorescent probe for chemical sensing.
- Manganese-doped carbon dots,
- Manganese,
- Fluorescent sensors,
- Quantum yield
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