Citation: Zhang Ting, Liu Yaohua, Hu Bowen, Zhang Chunhua, Chen Yong, Liu Yu. A multi-color and white-light emissive cucurbituril/terpyridine/lanthanide supramolecular nanofiber[J]. Chinese Chemical Letters, ;2019, 30(5): 949-952. doi: 10.1016/j.cclet.2018.12.029 shu

A multi-color and white-light emissive cucurbituril/terpyridine/lanthanide supramolecular nanofiber

Zhang Ting ^a,b ,
Liu Yaohua ^b ,
Hu Bowen ^a,**, ,
Zhang Chunhua ^a ,
Chen Yong ^b,c ,
Liu Yu ^b,c,*,

a.
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
b.
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
c.
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China

bowenhu@hit.edu.cn

yuliu@nankai.edu.cn

Received Date: 2 November 2018
Revised Date: 5 December 2018
Accepted Date: 27 December 2018
Available Online: 27 May 2018

Figures(5)

Multi-color and white light luminescence materials based on supramolecular assemblies are attractive because of their potential applications in advanced light-emitting material. Herein, a cucurbit[8]urilenhanced lanthanide luminescent supramolecular assembly was constructed in a facile but efficient way using terpyridine imidozalium cations, cucurbit[8]urils and rare earth ions such as Tb³⁺ and Eu³⁺. Significantly, the resultant fibrous supramolecular assembly, with an average width of 15 nm, could emit remarkable lanthanide luminescence, which was ten times higher than the corresponding terpyridine/Ln³⁺ without cucurbit[8]uril. And the solid state luminescence of supramolecular assembly could be smartly and easily turned among blue, green, red and white by adjusting the molar ratios between Tb³⁺ and Eu³⁺. The enhanced white-light emission by supramolecular strategy may provide a new approach for smart and tunable solid luminescent materials.
- Lanthanide luminescence,
- Cucurbit[8]uril,
- Host-guest interaction,
- White-light emission,
- Supramolecular chemistry
1. [1]
  Y. Zhou, H.Y. Zhang, Z.Y. Zhang, Y. Liu, J. Am. Chem. Soc. 139(2017) 7168-7171. doi: 10.1021/jacs.7b03153
2. [2]
  L. Li, C.K. Tsung, Z. Yang, et al., Adv. Mater. 20(2008) 903-908. doi: 10.1002/(ISSN)1521-4095
3. [3]
  M.M. Lezhnina, T. Jüstel, H. Kätker, D.U. Wiechert, U.H. Kynast, Adv. Funct. Mater. 16(2006) 935-942. doi: 10.1002/(ISSN)1616-3028
4. [4]
  J. Thompson, R.I.R. Blyth, G. Gigli, R. Cingolani, Adv. Funct. Mater. 14(2004) 979-984. doi: 10.1002/(ISSN)1616-3028
5. [5]
  J.C.G. Bünzli, Chem. Rev. 110(2010) 2729-2755. doi: 10.1021/cr900362e
6. [6]
  S.S. Babu, V.K. Praveen, A. Ajayaghosh, Chem. Rev. 114(2014) 1973-2129. doi: 10.1021/cr400195e
7. [7]
  Y. Sagara, T. Kato, Nat. Chem. 1(2009) 605-610. doi: 10.1038/nchem.411
8. [8]
  X.M. Chen, Y. Chen, L. Liang, Q.J. Liu, Y. Liu, Macromol. Rapid Commun. 39(2018)1700869. doi: 10.1002/marc.v39.9
9. [9]
  X.L. Ni, S. Chen, Y. Yang, Z. Tao, J. Am. Chem. Soc. 138(2016) 6177-6183. doi: 10.1021/jacs.6b01223
10. [10]
  Q. Zhao, Y. Chen, S.H. Li, Y. Liu, Chem. Commun. 54(2018) 200-203. doi: 10.1039/C7CC08822A
11. [11]
  J. Lagona, P. Mukhopadhyay, S. Chakrabarti, L. Isaacs, Angew. Chem. Int. Ed. 44(2005) 4844-4870. doi: 10.1002/(ISSN)1521-3773
12. [12]
  E. Masson, X. Ling, R. Joseph, L. Kyeremeh-Mensah, X. Lu, RSC Adv. 2(2012) 1213-1247. doi: 10.1039/C1RA00768H
13. [13]
  Y. Zhang, Y. Chen, J. Li, L. Liang, Y. Liu, Acta Chim. Sinica 76(2018) 622-626. doi: 10.6023/A18040171
14. [14]
  Q. Zhao, Y. Chen, Y. Liu, Chin. Chem. Lett. 29(2018) 84-86. doi: 10.1016/j.cclet.2017.07.024
15. [15]
  Y. Chen, F. Huang, Z.T. Li, Y. Liu, Sci. China Chem. 61(2018) 979-992. doi: 10.1007/s11426-018-9337-4
16. [16]
  Y.H. Ko, E. Kim, I. Hwang, K. Kim, Chem. Commun. (2007) 1305-1315.
17. [17]
  S. Gurbuz, M. Idris, D. Tuncel, Org. Biomol. Chem. 13(2015) 330-347. doi: 10.1039/C4OB02065K
18. [18]
  A. Appel Eric, J. Dyson, J. Barrio, Z. Walsh, A. Scherman Oren, Angew. Chem. Int. Ed. 51(2012) 4185-4189. doi: 10.1002/anie.201108659
19. [19]
  Y. Lan, X.J. Loh, J. Geng, Z. Walsh, O.A. Scherman, Chem. Commun. 48(2012) 8757-8759. doi: 10.1039/c2cc34016j
20. [20]
  S.D. Choudhury, N. Barooah, V.K. Aswal, et al., Soft Matter 10(2014) 3485-3493. doi: 10.1039/c3sm52024b
21. [21]
  X.J. Loh, J. del Barrio, P.P.C. Toh, et al., Biomacromolecules 13(2012) 84-91. doi: 10.1021/bm201588m
22. [22]
  Y. Wang, D. Li, H. Wang, et al., Chem. Commun. 50(2014) 9390-9392. doi: 10.1039/C4CC03978E
23. [23]
  D. Jiao, J. Geng, J. Loh Xian, et al., Angew. Chem. Int. Ed. 51(2012) 9633-9637. doi: 10.1002/anie.v51.38
24. [24]
  X.J. Loh, J. del Barrio, T.C. Lee, O.A. Scherman, Chem. Commun. 50(2014) 3033-3035. doi: 10.1039/C3CC49074B
25. [25]
  G. Stephenson, R.M. Parker, Y. Lan, et al., Chem. Commun. 50(2014) 7048-7051. doi: 10.1039/C4CC01479K
26. [26]
  F. Tian, N. Cheng, N. Nouvel, J. Geng, O.A. Scherman, Langmuir 26(2010) 5323-5328. doi: 10.1021/la9033386
27. [27]
  F. Tian, D. Jiao, F. Biedermann, O.A. Scherman, Nat. Commun. 3(2012) 1207. doi: 10.1038/ncomms2198
28. [28]
  K.D. Zhang, J. Tian, D. Hanifi, et al., J. Am. Chem. Soc. 135(2013) 17913-17918. doi: 10.1021/ja4086935
29. [29]
  E.A. Appel, F. Biedermann, U. Rauwald, et al., J. Am. Chem. Soc. 132(2010) 14251-14260. doi: 10.1021/ja106362w
30. [30]
  R. Joseph, A. Nkrumah, R.J. Clark, E. Masson, J. Am. Chem. Soc.136(2014) 6602-6607. doi: 10.1021/ja4092165
31. [31]
  M. Raeisi, K. Kotturi, I. del Valle, et al., J. Am. Chem. Soc. 140(2018) 3371-3377. doi: 10.1021/jacs.7b13304
32. [32]
  O. Kotova, R. Daly, M.G. Cidália, et al., Angew. Chem. Int. Ed. 51(2012) 7208-7212. doi: 10.1002/anie.201201506
33. [33]
  P. Chen, Q. Li, S. Grindy, N. Holten-Andersen, J. Am. Chem. Soc. 137(2015) 11590-11593. doi: 10.1021/jacs.5b07394
34. [34]
  S.V. Eliseeva, J.C.G. Bunzli, Chem. Soc. Rev. 39(2010) 189-227. doi: 10.1039/B905604C
35. [35]
  J.C.G. Bunzli, C. Piguet, Chem. Soc. Rev. 34(2005) 1048-1077. doi: 10.1039/b406082m
36. [36]
  A. Tigaa Rodney, X. Aerken, A. Fuchs, A. de Bettencourt-Dias, Eur. J. Inorg. Chem. 2017(2017) 5310-5317. doi: 10.1002/ejic.201700655
37. [37]
  J. Liu, Y. Tan Cindy Soo, Z. Yu, et al., Adv. Mater. 29(2017)1605325. doi: 10.1002/adma.v29.22
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