Citation: Jia Qiong, Du Xusheng, Wang Chunyu, Meguellati Kamel. A one-pot synthesis of a self-included bisester-functionalized copillar[5]arene[J]. Chinese Chemical Letters, ;2019, 30(3): 721-724. doi: 10.1016/j.cclet.2018.12.015 shu

A one-pot synthesis of a self-included bisester-functionalized copillar[5]arene

a.
International Joint Research Laboratory of Nano-Micro Architecture Chemistry (NMAC), College of Chemistry, Jilin University, Changchun 130012, China
b.
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China

kamel_m@jlu.edu.cn

Received Date: 19 October 2018
Revised Date: 4 December 2018
Accepted Date: 12 December 2018
Available Online: 13 March 2018

Figures(4)

We report here a one-pot synthetic method for the synthesis of a bisester-functionalized copillar[5]arene (BECP5A) with yield up to 20%. The properties of BECP5A in solution and in solid state were deeply investigated with the aid of 1D and 2D NMR spectra and X-ray diffraction, showing that this molecule has a fully self-included conformation in chloroform and partial self-inclusion in DMSO, and the compound has an asymmetrical structure with only one self-included side in the cavity of pillar[5]arene in the solid state. This compound will be used as the precursor of complex systems such as polymers and mechanically interlocked molecules.
- Pillar[5]arene,
- One-pot reaction,
- Ester group,
- Supramolecular chemistry,
- X-ray crystal structure
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