Citation: Bai Lin-Ming, Yao Huan, Yang Liu-Pan, Zhang Wen, Jiang Wei. Molecular recognition and fluorescent sensing of urethane in water[J]. Chinese Chemical Letters, ;2019, 30(4): 881-884. doi: 10.1016/j.cclet.2018.11.033 shu

Molecular recognition and fluorescent sensing of urethane in water

Bai Lin-Ming ^a,b ,
Yao Huan ^b ,
Yang Liu-Pan ^b ,
Zhang Wen ^a,*, ,
Jiang Wei ^b,*,

a.
School of Science, Xi'an Jiaotong University, Xi'an 710049, China
b.
Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China

zhangwen@mail.xjtu.edu.cn

jiangw@sustc.edu.cn

Received Date: 24 October 2018
Revised Date: 27 November 2018
Accepted Date: 28 November 2018
Available Online: 2 April 2018

Figures(7)

Molecular recognition and fluorescent sensing of Group 2A carcinogen-urethane was achieved in aqueous solution. The molecular sensors are the endo-functionalized molecular tubes with amide protons in the hydrophobic cavity. ¹H NMR, fluorescence, and ITC titrations and single crystal X-ray crystallography reveal the binding stoichiometry, the binding affinities, and the driving forces. The binding is mainly driven by the hydrophobic effect through releasing the "high-energy" cavity water with minor contribution from hydrogen bonding. In addition, the syn-configured molecular tube was found to be a good fluorescent sensor for urethane in water (concentration range:6.2-60 μmol/L) and in beer (concentration range:22.9-60 μmol/L).
- Host-guest chemistry,
- Molecular recognition,
- Urethane,
- Fluorescent sensing
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