Citation: Rong Xiaohui, Gao Fei, Lu Yaxiang, Yang Kai, Hu Yongsheng. P2-type Na_0.6[Mg(Ⅱ)_0.3Mn(Ⅳ)_0.7]O₂ as a new model material for anionic redox reaction[J]. Chinese Chemical Letters, ;2018, 29(12): 1791-1794. doi: 10.1016/j.cclet.2018.11.023 shu

P2-type Na_0.6[Mg(Ⅱ)_0.3Mn(Ⅳ)_0.7]O₂ as a new model material for anionic redox reaction

Rong Xiaohui ^a,b,1 ,
Gao Fei ^a,1 ,
Lu Yaxiang ^b,*, ,
Yang Kai ^a ,
Hu Yongsheng ^b

a.
State Key Laboratory of Operation and Control of Renewable Energy and Storage Systems, China Electric Power Research Institute, Beijing 100192, China
b.
Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100190, China

yxlu@iphy.ac.cn

Received Date: 19 September 2018
Revised Date: 5 November 2018
Accepted Date: 16 November 2018
Available Online: 20 December 2018

Figures(4)

A new model material of Na_0.6[Mg(Ⅱ)_0.3Mn(Ⅳ)_0.7]O₂, with only Mg²⁺ and Mn⁴⁺ in the transition metal layers, is synthesized for the research of anionic redox reaction. The material delivers a capacity of~130 mAh/g with a long plateau at~4.2 V in the initial charge profile, indicating anionic redox reaction (ARR) involved during the initial desodiation process. In the following cycles, the reversible capacity can reach a high value of~210 mAh/g, which is probably derived from the participation of both ARR and Mn³⁺/Mn⁴⁺ redox couples, further proving the charge compensation from ARR during the initial charge and following cycles. The designed cathode material without Mn³⁺ helps avoid the influence of oxygen activity from transition metals, enabling the investigation of ARR without other distractions.
- Na-ion batteries,
- Layered oxide,
- Cathode,
- Anionic redox reaction,
- Na_0.6[Mg_0.3Mn_0.7]O₂
1. [1]
  J. Yan, X. Liu, B. Li, RSC Adv. 4(2014) 63268-63284. doi: 10.1039/C4RA12454E
2. [2]
  J. Hong, H. Gwon, S.K. Jung, K. Ku, K. Kang, J. Electrochem. Soc. 162(2015) A2447-A2467. doi: 10.1149/2.0071514jes
3. [3]
  J.W. Choi, D. Aurbach, Nat. Rev. Mater. 1(2016) 16013. doi: 10.1038/natrevmats.2016.13
4. [4]
  C. Zhao, Q. Wang, Y. Lu, et al., J. Phys. D-Appl. Phys. 50(2017) 183001. doi: 10.1088/1361-6463/aa646d
5. [5]
  M. Sathiya, G. Rousse, K. Ramesha, et al., Nat. Mater. 12(2013) 827-835. doi: 10.1038/nmat3699
6. [6]
  E. McCalla, A.M. Abakumov, M. Saubanère, et al., Science 350(2015) 1521-1516. doi: 10.1126/science.aac9715
7. [7]
  Y. Li, Y. Lu, C. Zhao, et al., Energy Storage Mater. 7(2017) 130-151. doi: 10.1016/j.ensm.2017.01.002
8. [8]
  C. Zhao, Q. Wang, Y. Lu, et al., Sci. Bull. 63(2018) 1125-1129. doi: 10.1016/j.scib.2018.07.018
9. [9]
  Y. Lu, C. Zhao, X. Qi, et al., Adv. Energy Mater. (2018) 1800108.
10. [10]
  N. Yabuuchi, R. Hara, K. Kubota, et al., J. Mater. Chem. A 2(2014) 16851-16855. doi: 10.1039/C4TA04351K
11. [11]
  N. Yabuuchi, R. Hara, M. Kajiyama, et al., Adv. Energy Mater. 4(2014) 1301453. doi: 10.1002/aenm.201301453
12. [12]
  K. Du, J. Zhu, G. Hu, et al., Energy Environ. Sci. 9(2016) 2575-2577. doi: 10.1039/C6EE01367H
13. [13]
  X. Rong, J. Liu, E. Hu, et al., Joule 2(2017) 125-140.
14. [14]
  E. de la Llave, E. Talaie, E. Levi, et al., Chem. Mater. 28(2016) 9064-9076. doi: 10.1021/acs.chemmater.6b04078
15. [15]
  C. Ma, J. Alvarado, J. Xu, et al., J. Am. Chem. Soc. (2017) 4835-4845.
16. [16]
  A.J. Perez, D. Batuk, M. Saubanère, et al., Chem. Mater. 28(2016) 8278-8288. doi: 10.1021/acs.chemmater.6b03338
17. [17]
  P. Rozier, M. Sathiya, A.R. Paulraj, et al., Electrochem. Commun. 53(2015) 29-32. doi: 10.1016/j.elecom.2015.02.001
1. [1]
  Zhuangzhuang Zhang , Yaru Qiao , Jun Zhao , Dai-Huo Liu , Mengmin Jia , Hongwei Tang , Liang Wang , Dongmei Dai , Bao Li . Fluorine-doped K_0.39Mn_0.77Ni_0.23O_1.9F_0.1 microspheres with highly reversible oxygen redox reaction for potassium-ion battery cathode. Chinese Chemical Letters, 2025, 36(3): 109907-. doi: 10.1016/j.cclet.2024.109907
2. [2]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
3. [3]
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4. [4]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
5. [5]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
6. [6]
  Bin Feng , Tao Long , Ruotong Li , Yuan-Li Ding . Rationally constructing metallic Sn-ZnO heterostructure via in-situ Mn doping for high-rate Na-ion batteries. Chinese Chemical Letters, 2025, 36(2): 110273-. doi: 10.1016/j.cclet.2024.110273
7. [7]
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8. [8]
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10. [10]
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11. [11]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
12. [12]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
13. [13]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
14. [14]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
15. [15]
  Runjing Xu , Xin Gao , Ya Chen , Xiaodong Chen , Lifeng Cui . Research status and prospect of rechargeable magnesium ion batteries cathode materials. Chinese Chemical Letters, 2024, 35(11): 109852-. doi: 10.1016/j.cclet.2024.109852
16. [16]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
17. [17]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
18. [18]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
19. [19]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
20. [20]
  Fan Wu , Shaoyang Wu , Xin Ye , Yurong Ren , Peng Wei . Research progress of high-entropy cathode materials for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(4): 109851-. doi: 10.1016/j.cclet.2024.109851

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

P2-type Na0.6[Mg(Ⅱ)0.3Mn(Ⅳ)0.7]O2 as a new model material for anionic redox reaction

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通讯作者: 陈斌, bchen63@163.com

P2-type Na_0.6[Mg(Ⅱ)_0.3Mn(Ⅳ)_0.7]O₂ as a new model material for anionic redox reaction