Citation: Liu Hengqi, Zhao Depeng, Hu Pengfei, Wu Xiang. Ternary core-shell structured transition metal chalcogenide for hybrid electrochemical capacitor[J]. Chinese Chemical Letters, ;2018, 29(12): 1799-1803. doi: 10.1016/j.cclet.2018.11.019 shu

Ternary core-shell structured transition metal chalcogenide for hybrid electrochemical capacitor

School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China

wuxiang05@sut.edu.cn

Received Date: 4 November 2018
Revised Date: 14 November 2018
Accepted Date: 15 November 2018
Available Online: 17 December 2018

Figures(4)

Hybrid structured semiconductor nanomaterials possess excellent electrochemical performances owing to the synergistic effects from two components. Herein we report a novel CoMo₂S₄@Zn-Co-S core-shell structure as the electrode materials for asymmetric supercapacitor. The unique electrode structure is beneficial to rapid electron transport and the ion diffusion due to the existence of many vast channels. The as-synthesized core-shell structured electrode exhibits an overall improved electrochemical performance. Moreover, a quasi-solid state asymmetric supercapacitor is fabricated. It reveals a specific capacitance of 0.84 C/cm² collected at 4 mA/cm² and an energy density of 1.87 mWh/cm³ at a power density of 31.99 W/cm³.
- CoMo₂S₄@Zn-Co-S,
- Core-shell structure,
- Supercapacitor,
- Specific capacitance,
- High energy density
1. [1]
  Y. Jiao, Y. Liu, B.S. Yin, et al., Nano Energy 10(2014) 90-98. doi: 10.1016/j.nanoen.2014.09.002
2. [2]
  H. Yuan, L. Kong, T. Li, Q. Zhang, Chin. Chem. Lett. 28(2017) 2180-2194. doi: 10.1016/j.cclet.2017.11.038
3. [3]
  X. Wu, S.Y. Yao, Nano Energy 42(2017) 143-150. doi: 10.1016/j.nanoen.2017.10.058
4. [4]
  Y. Han, Q. Zhang, N.T. Hu, et al., Chin. Chem. Lett. 28(2017) 2269-2273. doi: 10.1016/j.cclet.2017.10.024
5. [5]
  W. Jiang, F. Hu, Q.Y. Yan, X. Wu, Inorg. Chem. Front. 4(2017) 1642-1648. doi: 10.1039/C7QI00391A
6. [6]
  H. Heydari, S.E. Moosavifard, M. Shahraki, S. Elyasi, J. Energy Chem. 26(2017) 762-767. doi: 10.1016/j.jechem.2017.03.007
7. [7]
  W. Jiang, F. Hu, S.Y. Yao, Z.P. Sun, X. Wu, Mater. Res. Bullet. 93(2017) 303-309. doi: 10.1016/j.materresbull.2017.05.036
8. [8]
  J.R. Miller, P. Simon, Science 321(2008) 651-652. doi: 10.1126/science.1158736
9. [9]
  Z.G. Zhang, X. Huang, H. Li, et al., J. Energy Chem. 26(2017) 1260-1266. doi: 10.1016/j.jechem.2017.09.025
10. [10]
  L. Xing, Y.D. Dong, F. Hu, X. Wu, A. Umar, Dalton Trans. 47(2018) 5687-5694. doi: 10.1039/C8DT00750K
11. [11]
  K. Deori, S.K. Ujjain, R.K. Sharma, S. Deka, ACS Appl. Mater. Interfaces 5(2013) 10665-10672. doi: 10.1021/am4027482
12. [12]
  C. Liu, W. Jiang, F. Hu, X. Wu, D.F. Xue, Inorg. Chem. Front. 5(2018) 835-843. doi: 10.1039/C8QI00010G
13. [13]
  Q.F. Wang, X.F. Wang, J. Xu, et al., Nano Energy 8(2014) 44-51. doi: 10.1016/j.nanoen.2014.05.014
14. [14]
  X. Wu, Z.C. Han, X. Zheng, et al., Nano Energy 31(2017) 410-417. doi: 10.1016/j.nanoen.2016.11.035
15. [15]
  C. Liu, X. Wu, Mater. Res. Bullet. 103(2018) 55-62. doi: 10.1016/j.materresbull.2018.03.014
16. [16]
  H.C. Chen, J.J. Jiang, L. Zhang, et al., J. Power Sour. 254(2014) 249-257. doi: 10.1016/j.jpowsour.2013.12.092
17. [17]
  J. Pu, Z.H. Wang, K.L. Wu, N. Yu, E.H. Sheng, Phys. Chem. Chem. Phys. 16(2014) 785-791. doi: 10.1039/C3CP54192D
18. [18]
  W. Cheng, C.L. Chen, Y. Yu, et al., Chin. J. Chem. 8(2017) 1303-1308.
19. [19]
  C. Li, J. Balamurugan, N.H. Kim, J.H. Lee, Adv. Energy Mater. 8(2018) 1-12.
20. [20]
  X.C. Xiao, G.F. Wang, M.M. Zhang, et al., Ionics 24(2018) 2435-2443. doi: 10.1007/s11581-017-2354-9
21. [21]
  J. Wu, X.L. Shi, W. Song, et al., Nano Energy 45(2018) 439-447. doi: 10.1016/j.nanoen.2018.01.024
22. [22]
  X. Zheng, Y. Jiao, F. Chai, et al., J. Colloid Interface Sci. 457(2015) 345-352. doi: 10.1016/j.jcis.2015.07.023
23. [23]
  D.P. Zhao, F. Hu, A. Umar, X. Wu, New J. Chem. 42(2018) 7399-7406. doi: 10.1039/C8NJ00935J
24. [24]
  J. Wang, X. Zhang, Q.L. Wei, et al., Nano Energy 19(2016) 222-234. doi: 10.1016/j.nanoen.2015.10.036
25. [25]
  B.L. Ellis, P. Knauth, T. Djenizian, Adv. Mater. 26(2014) 3368-3397. doi: 10.1002/adma.v26.21
26. [26]
  W. Hu, R.Q. Chen, W. Xie, et al., ACS Appl. Mater. Interfaces 6(2014) 19318-19326. doi: 10.1021/am5053784
27. [27]
  L. Zheng, Y. Xu, D. Jin, Y. Xie, Chem.-Asian. J. 6(2011) 1505-1514. doi: 10.1002/asia.v6.6
28. [28]
  J.M. Ko, D. Soundarajan, J.H. Park, et al., Curr. Appl. Phys. 12(2012) 341-345. doi: 10.1016/j.cap.2011.07.029
29. [29]
  H. Yi, H.W. Wang, Y.T. Jing, T.Q. Peng, X.F. Wang, J. Power Sour. 285(2015) 281-290. doi: 10.1016/j.jpowsour.2015.03.106
30. [30]
  M. Kim, Y.H. Wang, K. Min, J. Kim, Electrochim. Acta 113(2013) 322-331. doi: 10.1016/j.electacta.2013.09.058
31. [31]
  J.X. Gou, S.L. Xie, Y.R. Liu, C.G. Liu, Electrochim. Acta 210(2016) 915-924. doi: 10.1016/j.electacta.2016.05.213
32. [32]
  L.F. Shen, Q. Che, H.S. Li, X.G. Zhang, Adv. Funct. Mater. 24(2014) 2630-2637. doi: 10.1002/adfm.v24.18
33. [33]
  M.F. El-Kady, V. Strong, S. Dubin, R.B. Kaner, Science 335(2012) 1326-1330. doi: 10.1126/science.1216744
34. [34]
  L.Y. Yuan, B. Yao, B. Hu, et al., Energy Environ. Sci. 6(2013) 470-476. doi: 10.1039/c2ee23977a
35. [35]
  L.Y. Yuan, X.H. Lu, X. Xiao, et al., ACS Nano 6(2012) 656-661. doi: 10.1021/nn2041279
36. [36]
  Z.J. Fan, J. Yan, T. Wei, et al., Adv. Funct. Mater. 21(2011) 2366-2375. doi: 10.1002/adfm.v21.12
37. [37]
  D.Z. Kong, C.W. Chen, Y. Wang, et al., J. Mater. Chem. A 3(2015) 16150-16161. doi: 10.1039/C5TA03469H
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