Citation: Jian Zelang, Wang Wentao, Wang Maoyu, Wang Yan, AuYeung Nick, Liu Miao, Feng Zhenxing. Al₂O₃ coated LiCoO₂ as cathode for high-capacity and long-cycling Li-ion batteries[J]. Chinese Chemical Letters, ;2018, 29(12): 1768-1772. doi: 10.1016/j.cclet.2018.11.002 shu

Al₂O₃ coated LiCoO₂ as cathode for high-capacity and long-cycling Li-ion batteries

Jian Zelang ^a,b,1 ,
Wang Wentao ^a,1 ,
Wang Maoyu ^a ,
Wang Yan ^a ,
AuYeung Nick ^a ,
Liu Miao ^c ,
Feng Zhenxing ^a,*,

a.
School of Chemical, Biological, and Environmental Engineering, Oregon State University, Corvallis OR 97331, United States
b.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
c.
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

zhenxing.feng@oregonstate.edu

Received Date: 7 October 2018
Revised Date: 1 November 2018
Accepted Date: 2 November 2018
Available Online: 3 December 2018

Figures(5)

Lithium-ion batteries (LIBs) as energy storage devices play an important role in all aspects of our life. The increasing energy demand of the society requires LIBs with higher energy density and better performance. We here develop a new and easy-to-scaleup sol-gel method to coat a surface protection layer on commercial LiCoO₂ cathode. We demonstrate that a proper thickness can improve the cycling life with a higher cut-off potential (4.5 V), larger energy capacity (180 mAh/g at 0.5C) and better energy density (35% more compared to non-coated LiCoO₂). The mechanism of the protection layer is also revealed by a combination of electron microscopy and synchrotron X-ray spectroscopy.
- Lithium-ion batteries,
- Al₂O₃ coating,
- High-capacity,
- Long-cycling,
- X-ray absorption spectroscopy
1. [1]
  T. Nagura, K. Tazawa, Batteries Sol. Cells 9(1990) 20.
2. [2]
  K. Ozawa, Solid State Ionics 69(1994) 212-221. doi: 10.1016/0167-2738(94)90411-1
3. [3]
  K. Zaghib, M. Armand, M. Gauthier, J. Electrochem. Soc. 145(1998) 3135-3140. doi: 10.1149/1.1838776
4. [4]
  Q. Cao, H. Zhang, G. Wang, et al., Electrochem. Commun. 9(2007) 1228-1232. doi: 10.1016/j.elecom.2007.01.017
5. [5]
  L. Liu, Z. Wang, H. Li, L. Chen, X. Huang, Solid State Ionics 152(2002) 341-346.
6. [6]
  Z. Chen, J. Dahn, Electrochim. Acta 49(2004) 1079-1090. doi: 10.1016/j.electacta.2003.10.019
7. [7]
  L. Dahéron, R. Dedryvere, H. Martinez, et al., Chem. Mater. 21(2009) 5607-5616. doi: 10.1021/cm901972e
8. [8]
  H. Wang, Y.I. Jang, B. Huang, D.R. Sadoway, Y.M. Chiang, J. Electrochem. Soc.146(1999) 473-480. doi: 10.1149/1.1391631
9. [9]
  S. Verdier, L. El Ouatani, R. Dedryvere, et al., J. Electrochem. Soc. 154(2007) A1088-A1099. doi: 10.1149/1.2789299
10. [10]
  A. Zhou, J. Xu, X. Dai, et al., J. Power Sources 322(2016) 10-16. doi: 10.1016/j.jpowsour.2016.04.092
11. [11]
  Y.K. Sun, S.W. Cho, S.T. Myung, K. Amine, J. Prakash, Electrochim. Acta 53(2007) 1013-1019. doi: 10.1016/j.electacta.2007.08.032
12. [12]
  B. Hwang, C. Chen, M. Cheng, R. Santhanam, K. Ragavendran, J. Power Sources 195(2010) 4255-4265. doi: 10.1016/j.jpowsour.2010.01.040
13. [13]
  Y. Kim, G.M. Veith, J. Nanda, R.R. Unocic, M. Chi, N.J. Dudney, Electrochim. Acta 56(2011) 6573-6580. doi: 10.1016/j.electacta.2011.03.070
14. [14]
  Y.S. Jung, P. Lu, A.S. Cavanagh, et al., Adv. Energy Mater. 3(2013) 213-219. doi: 10.1002/aenm.v3.2
15. [15]
  I.D. Scott, Y.S. Jung, A.S. Cavanagh, et al., Nano Lett. 11(2010) 414-418.
16. [16]
  H.M. Cheng, F.M. Wang, J.P. Chu, et al., J. Phys. Chem. C 116(2012) 7629-7637.
17. [17]
  J.S. Park, A.U. Mane, J.W. Elam, J.R. Croy, ACS Omega 2(2017) 3724-3729. doi: 10.1021/acsomega.7b00605
18. [18]
  S. Boukhalfa, K. Evanoff, G. Yushin, Energ. Environ. Sci. 5(2012) 6872-6879. doi: 10.1039/c2ee21110f
19. [19]
  W.T. Jeong, K.S. Lee, J. Power Sources 104(2002) 195-200. doi: 10.1016/S0378-7753(01)00916-8
20. [20]
  T. Ohzuku, H. Tomura, K. Sawai, J. Electrochem. Soc. 144(1997) 3496-3500. doi: 10.1149/1.1838039
21. [21]
  W. Lu, J. Zhang, J. Xu, X. Wu, L. Chen, ACS Appl. Mater. Interfaces 9(2017) 19313-19318. doi: 10.1021/acsami.7b03024
22. [22]
  D. Zuo, G. Tian, D. Chen, K. Shu, Int. J. Electrochem. Sci. 12(2017) 5044-5057.
23. [23]
  J. Xie, J. Zhao, Y. Liu, et al., Nano Research 10(2017) 3754-3764. doi: 10.1007/s12274-017-1588-1
24. [24]
  M. Xie, T. Hu, L. Yang, Y. Zhou, RSC Adv. 6(2016) 63250-63255. doi: 10.1039/C6RA10531A
25. [25]
  Z. Feng, M. McBriarty, A. Mane, et al., RSC Adv. 4(2014) 64608-64616. doi: 10.1039/C4RA14140G
26. [26]
  Z. Weng, Y. Wu, M. Wang, et al., Nat. Commun. 9(2018) 415. doi: 10.1038/s41467-018-02819-7
27. [27]
  B. Pan, J. Huang, M. He, et al., ChemSusChem 9(2016) 595-599. doi: 10.1002/cssc.201501557
28. [28]
  M. He, C.C. Su, Z. Feng, et al., Adv. Energy Mater. 7(2017) 1700179.
29. [29]
  C. Wei, Z. Feng, M. Baisariyev, et al., Chem. Mater. 28(2016) 4129-4133. doi: 10.1021/acs.chemmater.6b00713
30. [30]
  C. Wei, Z. Feng, G.G. Scherer, et al., Adv. Mater. 29(2017) 1606800. doi: 10.1002/adma.201606800
31. [31]
  K. Persson, Materials Project (2014), doi: http://dx.doi.org/10.17188/1187823.
32. [32]
  S. Xu, R.M. Jacobs, H.M. Nguyen, et al., J. Mater. Chem. A 3(2015) 17248-17272. doi: 10.1039/C5TA01664A
33. [33]
  S.Y. Kim, Y. Qi, J. Electrochem. Soc. 161(2014) F3137-F3143. doi: 10.1149/2.0301414jes
34. [34]
  S. Hao, C. Wolverton, J. Phy. Chem. C 117(2013) 8009-8013. doi: 10.1021/jp311982d
1. [1]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
2. [2]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
3. [3]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
4. [4]
  Guihuang Fang , Ying Liu , Yangyang Feng , Ying Pan , Hongwei Yang , Yongchuan Liu , Maoxiang Wu . Tuning the ion-dipole interactions between fluoro and carbonyl (EC) by electrolyte design for stable lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 110385-. doi: 10.1016/j.cclet.2024.110385
5. [5]
  Hui Gu , Mingyue Gao , Kuan Shen , Tianli Zhang , Junhao Zhang , Xiangjun Zheng , Xingmei Guo , Yuanjun Liu , Fu Cao , Hongxing Gu , Qinghong Kong , Shenglin Xiong . F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage. Chinese Chemical Letters, 2024, 35(9): 109273-. doi: 10.1016/j.cclet.2023.109273
6. [6]
  Zhe Wang , Li-Peng Hou , Qian-Kui Zhang , Nan Yao , Aibing Chen , Jia-Qi Huang , Xue-Qiang Zhang . High-performance localized high-concentration electrolytes by diluent design for long-cycling lithium metal batteries. Chinese Chemical Letters, 2024, 35(4): 108570-. doi: 10.1016/j.cclet.2023.108570
7. [7]
  Peng Zhou , Ziang Jiang , Yang Li , Peng Xiao , Feixiang Wu . Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance. Chinese Chemical Letters, 2024, 35(8): 109467-. doi: 10.1016/j.cclet.2023.109467
8. [8]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
9. [9]
  Wendi Dou , Guangying Wan , Tiefeng Liu , Lin Han , Wu Zhang , Chuang Sun , Rensheng Song , Jianhui Zheng , Yujing Liu , Xinyong Tao . Conductive composite binder for recyclable LiFePO₄ cathode. Chinese Chemical Letters, 2024, 35(11): 109389-. doi: 10.1016/j.cclet.2023.109389
10. [10]
  Tengfei Yang , Jingshuai Xiao , Xiao Sun , Yan Song , Chaozheng He . Facilitating the polysulfides conversion kinetics by porous LaOCl nanofibers towards long-cycling lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(3): 109691-. doi: 10.1016/j.cclet.2024.109691
11. [11]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309
12. [12]
  Xin Li , Ling Zhang , Yunyan Fan , Shaojing Lin , Yong Lin , Yongsheng Ying , Meijiao Hu , Haiying Gao , Xianri Xu , Zhongbiao Xia , Xinchuan Lin , Junjie Lu , Xiang Han . Carbon interconnected microsized Si film toward high energy room temperature solid-state lithium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109776-. doi: 10.1016/j.cclet.2024.109776
13. [13]
  Huanyan Liu , Jiajun Long , Hua Yu , Shichao Zhang , Wenbo Liu . Rational design of highly conductive and stable 3D flexible composite current collector for high performance lithium-ion battery electrodes. Chinese Chemical Letters, 2025, 36(3): 109712-. doi: 10.1016/j.cclet.2024.109712
14. [14]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
15. [15]
  Yan-Jiang Li , Shu-Lei Chou , Yao Xiao . Detecting dynamic structural evolution based on in-situ high-energy X-ray diffraction technology for sodium layered oxide cathodes. Chinese Chemical Letters, 2025, 36(2): 110389-. doi: 10.1016/j.cclet.2024.110389
16. [16]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
17. [17]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
18. [18]
  Yang LIU , Lijun WANG , Hongyu WANG , Zhidong CHEN , Lin SUN . Surface and interface modification of porous silicon anodes in lithium-ion batteries by the introduction of heterogeneous atoms and hybrid encapsulation. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 773-785. doi: 10.11862/CJIC.20250015
19. [19]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
20. [20]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(1249)
HTML views(184)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Al2O3 coated LiCoO2 as cathode for high-capacity and long-cycling Li-ion batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Al₂O₃ coated LiCoO₂ as cathode for high-capacity and long-cycling Li-ion batteries