Citation: Zheng Xiuli, Miao Qi, Wang Wenzhi, Qu Da-Hui. Constructing supramolecular polymers from phototrigger containing monomer[J]. Chinese Chemical Letters, ;2018, 29(11): 1621-1624. doi: 10.1016/j.cclet.2018.04.002 shu

Constructing supramolecular polymers from phototrigger containing monomer

Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai 200237, China

Corresponding author: Qu Da-Hui, dahui_qu@ecust.edu.cn
Received Date: 23 February 2018
Revised Date: 9 March 2018
Accepted Date: 2 April 2018
Available Online: 4 November 2018

Figures(6)

A new type of photo-induced supramolecular polymer was fabricated by host-guest interaction from a phototrigger containing building block. A dibenzo-24-crown-8 (DB24C8) macrocycle and dibenzylammonium (DBA) site containing linear monomer was designed and synthesized. The coumarin, as a photocleavable protector, was introduced to the terminal of the monomer. When exposed to the UV light, the coumarin unit would be cleavaged and the monomer without terminal coumarin can self-assemble into supramolecular polymers via the host-guest interaction between DB24C8 moieties and DBA units. Increasing the concentration of the monomer, the supramolecular polymers will convert to supramolecular organogel by cross-linking with each other.
- Supramolecular polymer,
- Host-guest recognition,
- Photo-responsive,
- Crown ether
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