Citation: Gong Wanbing, Chen Chun, Wang Haojie, Fan Ruoyu, Zhang Haimin, Wang Guozhong, Zhao Huijun. Sulfonate group modified Ni catalyst for highly efficient liquid-phase selective hydrogenation of bio-derived furfural[J]. Chinese Chemical Letters, ;2018, 29(11): 1617-1620. doi: 10.1016/j.cclet.2018.03.030 shu

Sulfonate group modified Ni catalyst for highly efficient liquid-phase selective hydrogenation of bio-derived furfural

Gong Wanbing ^a,b ,
Chen Chun ^a,*,, ,
Wang Haojie ^a,b ,
Fan Ruoyu ^a,b ,
Zhang Haimin ^a ,
Wang Guozhong ^a ,
Zhao Huijun ^a,c,*,,

a.
Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China
b.
University of Science and Technology of China, Hefei 230026, China
c.
Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University, Queensland 4222, Australia

Corresponding author: Chen Chun, chenchun2013@issp.ac.cn Zhao Huijun, h.zhao@griffith.edu.au

Received Date: 14 January 2018
Revised Date: 14 March 2018
Accepted Date: 26 March 2018
Available Online: 27 November 2018

Figures(1)

The liquid-phase furfural (FAL) hydrogenation to furfuryl alcohol (FOL) and tetrahydrofurfuryl alcohol (THFOL) was investigated using sulfonate group (-SO₃H) grafted activated carbon (AC) supported Ni catalyst, which was prepared and activated simultaneously by liquid phase reduction method. This functionalized nickel catalyst demonstrated an enhanced catalytic performance for selective hydrogenation of FAL, in which almost 100% FOL (< 80℃) and THFOL (>100℃) selectivity with complete conversion was obtained, respectively. More importantly, the conversion of transfer hydrogenation of FAL to FOL also can reach almost 100% under optimal conditions (140℃, 4.0 h). The effect of -SO₃H was evaluated and systematically analyzed by the combination of reaction performance and physico-chemical characterizations. Cycling test proved the prepared catalyst could be recycled and reused for several times without noticeably reducing catalytic activity of hydrogenation.
- Furfural,
- Nickel,
- Sulfonate group,
- Liquid-phase,
- Hydrogenation
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