Citation: Li Zhaozhong, Li Yang, Wang Dong, Cui Qing, Li Zhengqiang, Wang Lei, Yang Huai. Unique fluorescence properties of a self-assembling bis-pyrene molecule[J]. Chinese Chemical Letters, ;2018, 29(11): 1645-1647. doi: 10.1016/j.cclet.2018.01.056 shu

Unique fluorescence properties of a self-assembling bis-pyrene molecule

Li Zhaozhong ^a,b ,
Li Yang ^a ,
Wang Dong ^a ,
Cui Qing ^a ,
Li Zhengqiang ^a ,
Wang Lei ^a,b,, ,
Yang Huai ^a,c,,

a.
Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
b.
National Center for Nanoscience and Technology(NCNST), Beijing 100190, China
c.
Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China

Corresponding author: Wang Lei, wanglei@nanoctr.cn Yang Huai, yanghuai@mater.ustb.edu.cn
Received Date: 13 December 2017
Revised Date: 26 January 2018
Accepted Date: 30 January 2018
Available Online: 5 November 2018

Figures(5)

A self-assembling bis-pyrene (BP) molecule with π-π interactions was designed and synthesized. In condensed state, the BP self-assembled into highly-ordered mesophase at room temperature, which was characterized by using differential scanning calorimetry (DSC), polarized optical microscope (POM), and 1D wide angle X-ray diffraction (WAXD) techniques. In solution, the BP self-assembled into nanofibers in the mixed dichloromethane and hexane (1:1 volume ratio) solvent. Interestingly, the BP was not fluorescent when dissolved in dichloromethane solution. However, the self-assembled nanostructures of BP in the mixed solvent showed high intensity of green fluorescence. The advantages of self-assembly and fluorescence feature exhibited that BP could be promising fluorescence nanoprobes or nanosensors for various applications.
- Bis-pyrene,
- Fluorescence,
- Self-assembly,
- Mesophase,
- π-π Interaction
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