Citation: Hu Di, Wang Lu, Wang Feng, Wang Jide. Active carbon supported S-promoted Bi catalysts for acetylene hydrochlorination reaction[J]. Chinese Chemical Letters, ;2018, 29(9): 1413-1416. doi: 10.1016/j.cclet.2017.12.017 shu

Active carbon supported S-promoted Bi catalysts for acetylene hydrochlorination reaction

Key Laboratory of Oil & Gas Fine Chemicals Ministry of Education & Xinjiang Uyghur Autonomous Region, Xinjiang University, Urumqi 830046, China

Corresponding author: Wang Feng, wangfeng62@126.com Wang Jide, awangjd@126.com
Received Date: 5 June 2017
Revised Date: 28 November 2017
Accepted Date: 22 December 2017
Available Online: 26 September 2017

Figures(3)

In the present work, the sulfur doped bismuth-based catalysts were prepared by incipient wetness impregnation method and used for the hydrochlorination of acetylene to vinyl chloride monomer (VCM) in a fixed-bed reactor. The effect of introduction of S was characterized by N₂ adsorption-desorption, powder X-ray diffraction, transmission electron microscopy, thermogravimetric analysis, temperature-programmed reduction and X-ray photoelectron spectroscopy. The characterization results indicated that the doping of S resulted in the increase of Brunauer-Emmett-Teller (BET) surface areas and decrease of active species particle size for the Bi-based catalysts, which led to more accessible active sites, and consequently boosted the catalytic hydrochlorination activity. The effect of H₂SO₄ concentration on the activity of this type catalyst was examined, and the results showed that there is an optimal loading of H₂SO₄ (S/Bi=0.5 mol/mol), at which the conversion of C₂H₂ was enhanced to 81% under the reaction condition and coke deposition is a main reason for the deactivation of catalyst.
- Bi catalyst,
- Acetylene hydrochlorination,
- Sulfur doped,
- Active carbon,
- Acetylene conversion
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