Citation: Zhang Na, Hong Luying, Geng Aifang, Yan Jinghui, Yao Shuang, Zhang Zhiming. Extended structural materials constructed from sulfate-centered Preyssler-type polyoxometalate with excellent electrocatalytic property[J]. Chinese Chemical Letters, ;2018, 29(9): 1409-1412. doi: 10.1016/j.cclet.2017.12.003 shu

Extended structural materials constructed from sulfate-centered Preyssler-type polyoxometalate with excellent electrocatalytic property

Zhang Na ^a,b ,
Hong Luying ^a ,
Geng Aifang ^a,, ,
Yan Jinghui ^a ,
Yao Shuang ^a,b,, ,
Zhang Zhiming ^b

a.
College of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China
b.
Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, China

Corresponding author: Geng Aifang, gengaf0687@sina.com Yao Shuang, shuangyao@email.tjut.edu.cn
Received Date: 24 September 2017
Revised Date: 17 November 2017
Accepted Date: 4 December 2017
Available Online: 11 September 2017

Figures(5)

Sulfate-centered Preyssler-type polyoxometalate was used as the precursor to react with transition metal cations and organic ligand for constructing inorganic-organic hybrid materials {H[Ni₂(H₂O)₄(Htrz)₃]₂(KS₅W₃₀O₁₁₀)}·18H₂O (trz=1, 2, 4-triazole) (1), which was characterized by single crystal X-ray diffraction analysis, energy-dispersive X-ray (EDX), power X-ray diffraction (PXRD), IR spectra and thermogravimetric (TG) analyses. In 1, the cylindrical vacancy of the inorganic crown-type anion {S₅W₃₀O₁₁₀} captures a K⁺ ion resulting in the anion {KS₅W₃₀O₁₁₀}^9-, which was further connected by dimeric[Ni₂(H₂O)₄(Htrz)₃]₂ metal-organic units into an one-dimensional (1D) chain-like structure. These 1D chains are further packed to form a three-dimensional (3D) supramolecular structure via Hbonding interactions. Here, the sulfate-centered Preyssler-typepolyoxometalate was firstly used to coordinate with transition metal cations and introduced into the inorganic-organic hybrid materials. Electrocatalytic study indicates that compound 1 exhibits good electrocatalytic activity toward reduction of H₂O₂ and NO₂^-.
- Preyssler-type,
- Polyoxometalate,
- Transition metal,
- Supramolecular structure,
- Electrocatalytic activity
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