Citation: Shen Shenghui, Deng Shengjue, Zhong Yu, Wu Jianbo, Wang Xiuli, Xia Xinhui, Tu Jiangping. Binder-free carbon fiber/TiNb₂O₇ composite electrode as superior high-rate anode for lithium ions batteries[J]. Chinese Chemical Letters, ;2017, 28(12): 2219-2222. doi: 10.1016/j.cclet.2017.11.031 shu

Binder-free carbon fiber/TiNb₂O₇ composite electrode as superior high-rate anode for lithium ions batteries

a.
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
b.
Zhejiang Provincial Key Laboratory for Cutting Tools, Taizhou University, Taizhou 318000, China

Corresponding author: Xia Xinhui, helloxxh@zju.edu.cn
Received Date: 29 October 2017
Revised Date: 19 November 2017
Accepted Date: 22 November 2017
Available Online: 24 December 2017

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Construction of advanced high-rate anodes is critical for the development of high-power lithium ion batteries (LIBs). In this work, we report a binder-free carbon fiber (CF)/titanium niobium oxide (TiNb₂O₇ (TNO)) composite electrode via a simple solvothermal method combined with heat treatment. Continuous TNO film consisting of cross-linked TNO nanoparticles of 30-50 nm is strongly anchored on the carbon fiber forming integrated CF/TNO composite electrode. Owing to the intimate threedimensional structure, the as-prepared CF/TNO electrode presents exceptional high-rate performance (245 mAh/g at 1 C, and 138 mAh/g at 80 C) and enhanced cyclability with a capacity of 150 mAh/g at the current density of 10 C after 1000 cycles. Our results demonstrate the CF/TNO electrode as efficient anode for application in high-power lithium ion batteries.
- Titanium niobium oxide,
- Integrated electrode,
- Anode,
- Lithium ion batteries,
- High power
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Binder-free carbon fiber/TiNb2O7 composite electrode as superior high-rate anode for lithium ions batteries

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通讯作者: 陈斌, bchen63@163.com

Binder-free carbon fiber/TiNb₂O₇ composite electrode as superior high-rate anode for lithium ions batteries