Citation: Huang Kesheng, Li Bing, Zhao Mingming, Qiu Jiaqing, Xue Huaiguo, Pang Huan. Synthesis of lithium metal silicates for lithium ion batteries[J]. Chinese Chemical Letters, ;2017, 28(12): 2195-2206. doi: 10.1016/j.cclet.2017.11.010 shu

Synthesis of lithium metal silicates for lithium ion batteries

College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, China

Author Bio: Kesheng Huang is currently a student at Yangzhou University, under supervision by Professor Huan Pang, at Yangzhou University of Chemistry and Chemical Engineering, in Jiangsu province in China. His research is mainly focused on the field of energy storage, like lithium batteries and supercapacitors

Huaiguo Xue received his Ph.D. degree in polymer chemistry from the Zhejiang University in 2002. He is currently a professor of physical chemistry and the dean of the College of Chemistry and Chemical Engineering at the Yangzhou University. His research interests focus on electrochemistry, functional polymer and biosensors
Huan Pang received his Ph.D. degree from Nanjing University in 2011. He then founded his research group in Anyang Normal University where he was appointed as a distinguished professor in 2013. He has now jointed Yangzhou University as a university distinguished professor. He has published more than 110 papers in peerreviewing journals including Chem. Soc. Rev., Adv. Mater., Energy Environ. Sci., with 3900 citations (H-index = 33). His research interests include the development of inorganic nanostructures and their applications in flexible electronics with a focus on energy devices
Corresponding author: Pang Huan, huanpangchem@hotmail.com; panghuan@yzu.edu.cn
Received Date: 11 September 2017
Revised Date: 7 November 2017
Accepted Date: 7 November 2017
Available Online: 9 December 2017

Figures(10)

The lithium metal silicates (Li₂MSiO₄) (where M=Mn, Fe, and Co) have a great potential in rechargeable lithium ion batteries as polyanion cathodes, due to the immanent merits such as superior electrochemical properties, low cost, and abundance. However, these merits are suffered from lower electrical and ionic conductivities, owing to the effect of poor lithium ion extraction/insertion kinetics. By building hybrid architectures, the integrated composites may afford much promoting activities towards lithium ion batteries compared with the bare ones. Kinds of synthetic methods such as template method, sol-gel method, and hydrothermal method have been successfully applied to prepare lithium metal silicates based compounds and composite materials. In this review, we aim to present a general view of Li₂MSiO₄ for the recent progress. The relationship between nanoarchitectures and electrochemical performances is discussed. In the end, we also summarize the opportunities and challenges about Li₂MSiO₄ nanomaterials recently.
- Li₂MSiO₄,
- Lithium ion battery,
- Electrochemical,
- Nanomaterial,
- High performance
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