Citation: Wang Fang, Huang Anmin, Yin Xiaoqian, Wang Wenshu, Chen Jianbo. Multilevel profiling and identification of Dalbergia odorifera and Dalbergia stevensonii by FTIR, NMR and GC/MS[J]. Chinese Chemical Letters, ;2018, 29(9): 1395-1398. doi: 10.1016/j.cclet.2017.11.007 shu

Multilevel profiling and identification of Dalbergia odorifera and Dalbergia stevensonii by FTIR, NMR and GC/MS

a.
Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, China
b.
Minzu University of China, Beijing 100081, China
c.
School of Life Sciences, Beijing University of Chinese Medicine, Beijing 100029, China

Corresponding author: Huang Anmin, hbham2000@sina.com Chen Jianbo, chenjianbo@bucm.edu.cn
Received Date: 30 August 2017
Revised Date: 6 November 2017
Accepted Date: 7 November 2017
Available Online: 8 September 2017

Figures(3)

As a rare and valuable wood and herbal material, Dalbergia odorifera is often counterfeited by Dalbergia stevensonii in the market. For the confident chemical identification of D. odorifera and D. stevensonii, the ethanol-benzene extractives are characterized by multiple metabolomics tools, including Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR), and gas chromatographymass spectrometry (GC/MS). Conventional FTIR spectroscopy, second derivative infrared (SD-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy are combined to interpret the functional groups of the ethanol-benzene extractives. Fingerprint-like characteristics make FTIR a rapid and accurate method to distinguish D. odorifera from D. stevensonii. Chemical differences of the extractives revealed by FTIR methods can be further confirmed by ¹H NMR and ¹³C NMR. Meanwhile, the volatile compounds in the extractives can be identified by GC/MS. The combination of FTIR, NMR and GC/MS makes it possible to obtain the multiple profiles of the ethanol-benzene extractives, which is essential for the confident chemical identification of D. odorifera and D. stevensonii.
- Dalbergia odorifera,
- Dalbergia stevensonii,
- FTIR,
- NMR,
- GC/MS
1. [1]
  M.A. Barrett, J.L. Brown, A.D. Yoder, Nature 499(2013) 29.
2. [2]
  H.L. Huang, F.S. Li, H.D. Huang, Agric. Sci. Technol. 16(2015) 2042-2539.
3. [3]
  M. Yu, K. Liu, L. Zhou, L. Zhao, S.Q. Liu, Holzforschung 70(2015) 127-136.
4. [4]
  P.J. McClure, G.D. Chavarria, E. Espinoza, Rapid Commun. Mass Spectrom. 29(2015) 783-788. doi: 10.1002/rcm.7163
5. [5]
  H. Wang, W.H. Dong, W.J. Zuo, et al., Fitoterapia 95(2014) 16-21. doi: 10.1016/j.fitote.2014.02.013
6. [6]
  H. Wang, W.L. Mei, Y.B. Zeng, et al., Phytochem. Lett. 9(2014) 168-173. doi: 10.1016/j.phytol.2014.06.008
7. [7]
  B. Sun, A. Huang, Y. Wang, J. Liu, J. Nat. Fibers 12(2014) 1-11.
8. [8]
  A. Kilic, P. Niemz, Eur. J. Wood Prod. 70(2012) 79-83. doi: 10.1007/s00107-010-0489-8
9. [9]
  E.M.A. Ajuomg, M.C. Breese, Eur. J. Wood Prod. 56(1998) 139-142. doi: 10.1007/s001070050285
10. [10]
  E.M.A. Ajuong, M. Redington, Wood Sci. Technol. 38(2004) 181-190. doi: 10.1007/s00226-004-0236-6
11. [11]
  C.W. Choi, Y.H. Choi, M.R. Cha, et al., Appl. Biol. Chem. 52(2009) 375-379.
12. [12]
  S.N. Wang, F.D. Zhang, A.M. Huang, Q. Zhou, Holzforschung 70(2016) 503-510. doi: 10.1515/hf-2015-0125
13. [13]
  M. Ek, G. Gellerstedt, G. Henriksson, Wood Chemistry and Wood Biotechnology, Walter de Gruyter GmbH & Co. KG, Berlin, 2009.
14. [14]
  I. Noda, J. Am. Chem. Soc. 111(1989) 8116-8118. doi: 10.1021/ja00203a008
15. [15]
  M.Y. Li, S.C. Cheng, D. Li, et al., Chin. Chem. Lett. 26(2015) 221-225. doi: 10.1016/j.cclet.2014.11.024
16. [16]
  M.C. Popescu, J. Froidevaux, P. Navi, C.M. Popescu, J. Mol. Struct. 1033(2013) 176-186. doi: 10.1016/j.molstruc.2012.08.035
17. [17]
  S.Q. Sun, Q. Zhou, J.B. Chen, Infrared Spectroscopy for Complex Mixtures:Applications in Food and Traditional Chinese Medicine, 10th, Chemical Industry Press, Beijing, 2011.
18. [18]
  X.H. Liu, C.H. Xu, S.Q. Sun, et al., Spectrochim. Acta A Mol. Biomol. Spectrosc. 97(2012) 290-296. doi: 10.1016/j.saa.2012.06.013
19. [19]
  A.C. Meilan, A.M. Goodman, M.G. Baron, J.G. Rodriguez, Cellulose 23(2016) 901-913. doi: 10.1007/s10570-015-0848-z
20. [20]
  B.H. Xu, G.J. Zhang, S.Q. Sun, et al., J. Mol. Struct. 1018(2012) 88-95. doi: 10.1016/j.molstruc.2011.12.017
21. [21]
  W.S. Gary, Vib. Spectrosc. 4(1992) 123-124. doi: 10.1016/0924-2031(92)87024-A
22. [22]
  A.M. Huang, Q. Zhou, J.L. Liu, B.H. Fei, S.Q. Sun, J. Mol. Struct. 833-834(2008) 160-166.
23. [23]
  S. Luo, Y.Q. Wu, J. Huang, Biobased Mater. Sci. Eng. 10(2012) 156-160.
24. [24]
  F.D. Zhang, C.H. Xu, M.Y. Li, A.M. Huang, S.Q. Sun, J. Mol. Struct. 1069(2014) 89-95. doi: 10.1016/j.molstruc.2014.01.085
25. [25]
  J. Font, N. Salvado, S. Buti, J. Enrich, Anal. Chim. Acta. 598(2007) 119-127. doi: 10.1016/j.aca.2007.07.021
26. [26]
  J. Zeng, X.L. Zhang, Z.M. Guo, et al., J. Chromatogr. A 1218(2011) 1749-1755. doi: 10.1016/j.chroma.2011.01.079
27. [27]
  E. Duquesnoy, V. Castola, J. Casanova, Carbohyd. Res. 343(2008) 893-902. doi: 10.1016/j.carres.2008.01.001
28. [28]
  R. M. Silverstein, F. X. Webster, D. J. Kiemle, Spectrometric Identification of Organic Compounds, John Wiley Inc. & Sons, Hoboken, 2005.
29. [29]
  T. Ogata, S. Yahara, R. Hisatsune, R. Konishi, T. Nohara, Chem. Pharm. Bull. 38(1990) 979-987.
30. [30]
  Y. Goda, M. Katayama, K. Ichikawa, et al., Chem. Pharm. Bull. 40(1992) 2452-2457. doi: 10.1248/cpb.40.2452
31. [31]
  R.X. Liu, M. Ye, H.Z. Guo, K.S. Bi, D. Guo, Rapid Commun. Mass Spectrom. 19(2005) 1557-1565. doi: 10.1002/(ISSN)1097-0231
32. [32]
  R.X. Liu, W. Wang, Q. Wang, K.S. Bi, D. Guo, Biomed. Chromatogr. 20(2006) 101-108. doi: 10.1002/(ISSN)1099-0801
1. [1]
  Xinzhi Ding , Chong Liu , Jing Niu , Nan Chen , Shutao Xu , Yingxu Wei , Zhongmin Liu . Solid-state NMR study of the stability of MOR framework aluminum. Chinese Journal of Structural Chemistry, 2024, 43(4): 100247-100247. doi: 10.1016/j.cjsc.2024.100247
2. [2]
  Ling-Hao Zhao , Hai-Wei Yan , Jian-Shuang Jiang , Xu Zhang , Xiang Yuan , Ya-Nan Yang , Pei-Cheng Zhang . Effective assignment of positional isomers in dimeric shikonin and its analogs by ¹H NMR spectroscopy. Chinese Chemical Letters, 2024, 35(5): 108863-. doi: 10.1016/j.cclet.2023.108863
3. [3]
  Honglin Gao , Chunlin Yuan , Hongyu Chen , Aiyi Dong , Pan Gao , Guangjin Hou . Surface gallium hydride on Ga2O3 polymorphs: A comparative solid-state NMR study. Chinese Journal of Structural Chemistry, 2025, 44(4): 100561-100561. doi: 10.1016/j.cjsc.2025.100561
4. [4]
  Runze Liu , Yankai Bian , Weili Dai . Qualitative and quantitative analysis of Brønsted and Lewis acid sites in zeolites: A combined probe-assisted 1H MAS NMR and NH3-TPD investigation. Chinese Journal of Structural Chemistry, 2024, 43(4): 100250-100250. doi: 10.1016/j.cjsc.2024.100250
5. [5]
  Guo-Ping Yin , Ya-Juan Li , Li Zhang , Ling-Gao Zeng , Xue-Mei Liu , Chang-Hua Hu . Citrinsorbicillin A, a novel homotrimeric sorbicillinoid isolated by LC-MS-guided with cytotoxic activity from the fungus Trichoderma citrinoviride HT-9. Chinese Chemical Letters, 2024, 35(8): 109035-. doi: 10.1016/j.cclet.2023.109035
6. [6]
  Pengyu Chen , Beibei Chen , Man He , Yuxi Zhou , Lei Lei , Jian Han , Bingsheng Zhou , Ligang Hu , Bin Hu . Nanoplastics and nano-ZnO facilitate Cd accumulation in zebrafish larvae via a distinct pathway: Revelation by LA-ICP-MS imaging. Chinese Chemical Letters, 2025, 36(2): 109908-. doi: 10.1016/j.cclet.2024.109908
7. [7]
  Dan Zhou , Liangjin Bao , Haoqi Long , Duo Zhou , Yuwei Xu , Bo Wang , Chuanqin Xia , Liang Xian , Chengbin Zheng . Capillary electrophoresis as sample introduction system for highly sensitive and interference-free determination of ⁹⁹Tc by ICP-MS. Chinese Chemical Letters, 2025, 36(4): 110093-. doi: 10.1016/j.cclet.2024.110093
8. [8]
  Wantong Zhang , Zixing Xu , Guofei Dai , Zhijian Li , Chunhui Deng . Removal of Microcystin-LR in lake water sample by hydrophilic mesoporous silica composites under high-throughput MALDI-TOF MS detection platform. Chinese Chemical Letters, 2024, 35(5): 109135-. doi: 10.1016/j.cclet.2023.109135
9. [9]
  Jun-Jie Fang , Zheng Liu , Yun-Peng Xie , Xing Lu . Superatomic Ag₅₈ nanoclusters incorporating a [MS₄@Ag₁₂]²⁺ (M = Mo or W) kernel show aggregation-induced emission. Chinese Chemical Letters, 2024, 35(10): 109345-. doi: 10.1016/j.cclet.2023.109345
10. [10]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
11. [11]
  Yong-Fang Shi , Sheng-Hua Zhou , Zuju Ma , Xin-Tao Wu , Hua Lin , Qi-Long Zhu . From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation. Chinese Journal of Structural Chemistry, 2025, 44(1): 100455-100455. doi: 10.1016/j.cjsc.2024.100455

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(2226)
HTML views(221)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142