Citation: Han Pei, Liu Tuanchun, Ji Xiaowei, Tang Shaokun. Morphology-controlled synthesis of mesoporous silica with co-template of surfactant P123 and ionic liquid[Dmim]Cl[J]. Chinese Chemical Letters, ;2018, 29(8): 1305-1309. doi: 10.1016/j.cclet.2017.10.042 shu

Morphology-controlled synthesis of mesoporous silica with co-template of surfactant P123 and ionic liquid[Dmim]Cl

Han Pei ^a ,
Liu Tuanchun ^a ,
Ji Xiaowei ^a ,
Tang Shaokun ^a,b,,

a.
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, China
b.
Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin University, Tianjin 300072, China

Corresponding author: Tang Shaokun, shktang@tju.edu.cn
Received Date: 5 May 2017
Revised Date: 31 October 2017
Accepted Date: 31 October 2017
Available Online: 20 August 2017

Figures(7)

Mesoporous silicas with different morphologies have attracted great interest in the fields of catalysis, separation and so on. In this study, silica hollow tubes with ordered mesopores were synthesized via a novel sol-gel method with an ionic liquid 1-decyl-3-methylimidazolium chloride ([Dmim]Cl) and a nonionic surfactant P123 (PEO₂₀PPO₇₀PEO₂₀) as the co-template. Coparatively, silica hollow spheres with disordered mesopores were synthesized with only[Dmim]Cl as the template. The template dosage is the key factor in controlling the morphology. The micelles assembly mechanism based on hydrogen bonding interactions is proposed to be responsible for the formation of the final silica morphology and mesostructure.
- Silica hollow spheres,
- Silica tubes,
- Mesoporous,
- Co-template,
- Ionic liquids,
- P123
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