Citation: Hu Jinwen, Zhao Chunyi, He Sheng, Tian Wenming, Hao Ce, Jin Shengye. Carrier dynamics in CsPbI₃ perovskite microcrystals synthesized in solution phase[J]. Chinese Chemical Letters, ;2018, 29(5): 699-702. doi: 10.1016/j.cclet.2017.10.005 shu

Carrier dynamics in CsPbI₃ perovskite microcrystals synthesized in solution phase

Hu Jinwen ^a,b ,
Zhao Chunyi ^b ,
He Sheng ^b ,
Tian Wenming ^b ,
Hao Ce ^a,, ,
Jin Shengye ^b,,

a.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Panjin 124221, China
b.
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Corresponding author: Hao Ce, haoce@dlut.edu.cn Jin Shengye, sjin@dicp.ac.cn
Received Date: 24 March 2017
Revised Date: 15 September 2017
Accepted Date: 11 October 2017
Available Online: 13 May 2017

Figures(4)

All-inorganic cesium lead halide perovskites (CsPbX₃, X=Cl^-, Br^-, I^-) could provide comparable optoelectronic properties as a promising class of materials for photovoltaic cell (PV), photodetector and light-emitting diode (LED) with enhanced thermal and moisture stabilities compared to organicinorganic lead halide species. However, fabrication of CsPbI₃ perovskite via facile solution process has been difficult due to instability of CsPbI₃ in the perovskite cubic phase in ambient air. Herein, we report the synthesis of CsPbI₃ perovskite microcrystals by low-temperature, catalyst-free, solution-phase method. By applying the time-resolve spectroscopic technique, we determine the carrier diffusion coefficient of 0.6-1.2 cm²/s, the intrinsic carrier lifetimes of 200-1300 ns and diffusion length of 4-10 μm in different individual CsPbI₃ perovskite microcrystals. Our results suggest the CsPbI₃ perovskite microcrystals synthesized by solution process exhibit high quality feature and are suitable for applications in optoelectronic devices.
- Carrier dynamics,
- CsPbI₃,
- Solution process,
- Perovskite
1. [1]
  W.S. Yang, J.H. Noh, N.J. Jeon, et al., Science 348(2015) 1234-1237. doi: 10.1126/science.aaa9272
2. [2]
  M.A. Green, A. Ho-Baillie, H.J. Snaith, Nat. Photonics 8(2014) 506-514. doi: 10.1038/nphoton.2014.134
3. [3]
  H.P. Zhou, Q. Chen, G. Li, et al., Science 345(2014) 542-546. doi: 10.1126/science.1254050
4. [4]
  J.A. Christians, R.C.M. Fung, P.V. Kamat, J. Am. Chem. Soc. 136(2014) 758-764. doi: 10.1021/ja411014k
5. [5]
  J.A. Christians, J.S. Manser, P.V. Kamat, J. Phys. Chem. Lett. 6(2015) 2086-2095. doi: 10.1021/acs.jpclett.5b00594
6. [6]
  G.R. Li, Z.K. Tan, D.W. Di, et al., Nano Lett. 15(2015) 2640-2644. doi: 10.1021/acs.nanolett.5b00235
7. [7]
  Z.K. Tan, R.S. Moghaddam, M.L. Lai, et al., Nat. Nanotechnol. 9(2014) 687-692. doi: 10.1038/nnano.2014.149
8. [8]
  L. Dou, Y.M. Yang, J. You, et al., Nat. Commun. 5(2014) 5404-5404. doi: 10.1038/ncomms6404
9. [9]
  Y.L. Guo, C. Liu, H. Tanaka, et al., J. Phys. Chem. Lett. 6(2015) 535-539. doi: 10.1021/jz502717g
10. [10]
  Y.H. Kim, H. Cho, J.H. Heo, et al., Adv. Mater. 27(2015) 1248-1254. doi: 10.1002/adma.201403751
11. [11]
  B.R. Sutherland, S. Hoogland, M.M. Adachi, et al., Acs Nano 8(2014) 10947-10952. doi: 10.1021/nn504856g
12. [12]
  G.C. Xing, N. Mathews, S.S. Lim, et al., Nat. Mater. 13(2014) 476-480. doi: 10.1038/nmat3911
13. [13]
  Q. Zhang, S.T. Ha, X.F. Liu, et al., Nano Lett. 14(2014) 5995-6001. doi: 10.1021/nl503057g
14. [14]
  F. Deschler, M. Price, S. Pathak, et al., J. Phys. Chem. Lett. 5(2014) 1421-1426. doi: 10.1021/jz5005285
15. [15]
  H.M. Zhu, Y.P. Fu, F. Meng, et al., Nat. Mater. 14(2015) 636-642. doi: 10.1038/nmat4271
16. [16]
  J.Z. Song, J.H. Li, X.M. Li, et al., Adv. Mater. 27(2015) 7162-7167. doi: 10.1002/adma.201502567
17. [17]
  J.H. Li, L.M. Xu, T. Wang, et al., Adv. Mater. 29(2017) 1603885. doi: 10.1002/adma.201603885
18. [18]
  W.S. Yang, B.W. Park, E.H. Jung, et al., Science 356(2017) 1376-1379. doi: 10.1126/science.aan2301
19. [19]
  Y. Han, S. Meyer, Y. Dkhissi, et al., J. Mater. Chem. A 3(2015) 8139-8147. doi: 10.1039/C5TA00358J
20. [20]
  G.E. Eperon, S.D. Stranks, C. Menelaou, et al., Energy Environ. Sci. 7(2014) 982-988. doi: 10.1039/c3ee43822h
21. [21]
  M. Kulbak, S. Gupta, N. Kedem, et al., J. Phys. Chem. Lett. 7(2016) 167-172. doi: 10.1021/acs.jpclett.5b02597
22. [22]
  G.E. Eperon, G.M. Paterno, R.J. Sutton, et al., J. Mater. Chem. A 3(2015) 19688-19695. doi: 10.1039/C5TA06398A
23. [23]
  M. Kulbak, D. Cahen, G. Hodes, J. Phys. Chem. Lett. 6(2015) 2452-2456. doi: 10.1021/acs.jpclett.5b00968
24. [24]
  R.J. Sutton, G.E. Eperon, L. Miranda, et al., Adv. Energy Mater. 6(2016) 1502458. doi: 10.1002/aenm.201502458
25. [25]
  R.E. Beal, D.J. Slotcavage, T. Leijtens, et al., J. Phys. Chem. Lett. 7(2016) 746-751. doi: 10.1021/acs.jpclett.6b00002
26. [26]
  J.B. Hoffman, A.L. Schleper, P.V. Kamat, J. Am. Chem. Soc.138(2016) 8603-8611. doi: 10.1021/jacs.6b04661
27. [27]
  G. Nedelcu, L. Protesescu, S. Yakunin, et al., Nano Lett. 15(2015) 5635-5640. doi: 10.1021/acs.nanolett.5b02404
28. [28]
  L. Protesescu, S. Yakunin, M.I. Bodnarchuk, et al., Nano Lett. 15(2015) 3692-3696. doi: 10.1021/nl5048779
29. [29]
  Y. Wang, X.M. Li, J.Z. Song, et al., Adv. Mater. 27(2015) 7101-7108. doi: 10.1002/adma.201503573
30. [30]
  N. Yantara, S. Bhaumik, F. Yan, et al., J. Phys. Chem. Lett. 6(2015) 4360-4364. doi: 10.1021/acs.jpclett.5b02011
31. [31]
  Y.P. Fu, H.M. Zhu, C.C. Stoumpos, et al., ACS Nano 10(2016) 7963-7972. doi: 10.1021/acsnano.6b03916
32. [32]
  S.W. Eaton, M. Lai, N.A. Gibson, et al., Proc. Natl. Acad. Sci. U. S. A. 113(2016) 1993-1998. doi: 10.1073/pnas.1600789113
33. [33]
  F.R. Hu, C.Y. Yin, H.C. Zhang, et al., Nano Lett. 16(2016) 6425-6430. doi: 10.1021/acs.nanolett.6b02874
34. [34]
  K. Park, J.W. Lee, J.D. Kim, et al., J. Phys. Chem. Lett. 7(2016) 3703-3710. doi: 10.1021/acs.jpclett.6b01821
35. [35]
  P.F. Luo, W. Xia, S.W. Zhou, et al., J. Phys. Chem. Lett. 7(2016) 3603-3608. doi: 10.1021/acs.jpclett.6b01576
36. [36]
  G.E. Eperon, G.M. Paterno, R.J. Sutton, et al., J. Mater. Chem. A 3(2015) 19688-19695. doi: 10.1039/C5TA06398A
37. [37]
  T.S. Ripolles, K. Nishinaka, Y. Ogomi, et al., Solar Energy Mater. Solar Cells 144(2016) 532-536. doi: 10.1016/j.solmat.2015.09.041
38. [38]
  W.M. Tian, C.Y. Zhao, J. Leng, et al., J. Am. Chem. Soc. 137(2015) 12458-12461. doi: 10.1021/jacs.5b08045
39. [39]
  W.M. Tian, J. Leng, C.Y. Zhao, et al., J. Am. Chem. Soc. 139(2017) 579-582. doi: 10.1021/jacs.6b10512
40. [40]
  W.M. Tian, R.R. Cui, J. Leng, et al., Angew. Chem. Int. Ed. 55(2016) 13067-13071. doi: 10.1002/anie.201606574
41. [41]
  C.Y. Zhao, W.M. Tian, J. Leng, et al., Sci. Bull. 61(2016) 665-669. doi: 10.1007/s11434-016-1036-8
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Carrier dynamics in CsPbI3 perovskite microcrystals synthesized in solution phase

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通讯作者: 陈斌, bchen63@163.com

Carrier dynamics in CsPbI₃ perovskite microcrystals synthesized in solution phase