Citation: Sun Xianglang, Zhao Dongbing, Li Zhong'an. Recent advances in the design of dopant-free hole transporting materials for highly efficient perovskite solar cells[J]. Chinese Chemical Letters, ;2018, 29(2): 219-231. doi: 10.1016/j.cclet.2017.09.038 shu

Recent advances in the design of dopant-free hole transporting materials for highly efficient perovskite solar cells

a.
Key Laboratory for Material Chemistry of Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Zhao Dongbing, Li Zhong'an,
Received Date: 30 June 2017
Revised Date: 12 September 2017
Accepted Date: 14 September 2017
Available Online: 15 February 2017

Figures(7)

Continuous success has been achieved for solution-processed inorganic-organic hybrid perovskite solar cells(PVSCs) in the past several years, in which organic charge transporting materials play an important role.At present, most of the commonly used hole-transporting materials(HTMs) such as spiro-OMeTAD derivatives for PVSCs require additional chemical doping process to ensure sufficient conductivity and shift the Fermi level towards the HOMO level for efficient hole transport and collection.However, this doping process not only increases the complexity and cost of device fabrication, but also decreases the device stability.Thus development of efficient dopant-free HTMs for PVSCs is highly desirable and remains as a major challenge in this field.In this review, we will summarize the recent advances in the molecular design of dopant-free HTMs for PVSCs.
- Perovskite solar cells,
- Hole transporting materials,
- Dopant-free,
- D-A structure,
- Star-shape
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