Citation: Xu Huanhuan, Wang Chaozhan, Wei Yinmao. A boronate affinity restricted-access material with external hydrophilic bottlebrush polymers for pretreatment of cis-diols in biological matrices[J]. Chinese Chemical Letters, ;2018, 29(3): 521-523. doi: 10.1016/j.cclet.2017.08.056 shu

A boronate affinity restricted-access material with external hydrophilic bottlebrush polymers for pretreatment of cis-diols in biological matrices

Synthetic and Natural Functional Molecule Chemistry of Ministry of Education Key Laboratory, Key Laboratory of Modern Separation Science in Shaanxi Province, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China

Corresponding author: Wang Chaozhan, czwang@nwu.edu.cn
Received Date: 25 April 2017
Revised Date: 30 August 2017
Accepted Date: 11 August 2017
Available Online: 1 March 2017

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Restricted-access materials (RAMs) have found their broad application in sample pretreatment of bioanalysis. Boronate affinity (BA) adsorption is a very efficient and facile method for isolation and enrichment of cis-diol containing biomolecules which are a large important group compounds in biosystems. However, preparation of BA-RAMs are rarely reported to date. In this study, a novel BA-RAM with external surface comprised of hydrophilic bottlebrush polymers was prepared exploiting the excellent capability of the bottlebrush polymers for protein exclusion. A diblock copolymer poly(3-acrylamidophenylboronic acid)-block-poly(2-hydroxyethyl methacrylate) (PAAPBA-b-PHEMA) was first grafted from the silica surface via surface-initiated reversible addition-fragmentation chain transfer polymerization (SI-RAFT), and poly(N-isopropylacrylamide) (PNIPAAm) was then grafted from the PHEMA via surface-initiated atom transfer radical polymerization (SI-ATRP) to yield the BA-RAM. The BARAM exhibits high selectivity to cis-diol containing small molecules and has good capability to exclude proteins. Its practical application in bioanalysis was tested by pretreatment of serum sample for analysis of catecholamines with high recoveries and good precision. The preparation strategy for the BA-RAM is very versatile and is easy to be expanded to other modes of RAMs.
- Restricted-access material,
- Boronate affinity,
- cis-Diol,
- Bioanalysis,
- Bottlebrush polymer
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