Citation: Wu Qiong, Deng Dan, Lu Kun, Wei Zhi-Xiang. D-A structural protean small molecule donor materials for solution-processed organic solar cells[J]. Chinese Chemical Letters, ;2017, 28(11): 2065-2077. doi: 10.1016/j.cclet.2017.08.046 shu

D-A structural protean small molecule donor materials for solution-processed organic solar cells

Wu Qiong ^a,b ,
Deng Dan ^a,, ,
Lu Kun ^a,, ,
Wei Zhi-Xiang ^a

a.
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Deng Dan, dengd@nanoctr.cn Lu Kun, lvk@nanoctr.cn
Received Date: 2 July 2017
Revised Date: 3 August 2017
Accepted Date: 23 August 2017
Available Online: 9 November 2017

Figures(11)

Under the synergistic effect of molecular design and devices engineering, small molecular organic solar cells have presented an unstoppable tendency for rapid development with putting forward donoracceptor (D-A) structures. Up to now, the highest power conversion efficiency of small molecules has exceeded 11%, comparable to that of polymers. In this review, we summarize the high performance small molecule donors in various classes of typical donor-acceptor (D-A) structures and discuss their relationships briefly.
- Small molecule donor materials,
- Bulk heterojunction solar cells,
- Donor-acceptor structures,
- Molecule design,
- Power conversion efficiency
1. [1]
  A. Mishra, P. Bäuerle, Angew. Chem. Int. Ed. 51(2012) 2020-2067. doi: 10.1002/anie.201102326
2. [2]
  H.W. Luo, Z.T. Liu, Chin. Chem. Lett. 27(2016) 1283-1292. doi: 10.1016/j.cclet.2016.07.003
3. [3]
  W. Ni, X. Wan, M. Li, Y. Wang, Y. Chen, Chem. Commun. 51(2015) 4936-4950. doi: 10.1039/C4CC09758K
4. [4]
  Y. Huang, E.J. Kramer, A.J. Heeger, G.C. Bazan, Chem. Rev. 114(2014) 7006-7043. doi: 10.1021/cr400353v
5. [5]
  C.J. Brabec, M. Heeney, I. McCulloch, J. Nelson, Chem. Soc. Rev. 40(2011) 1185-1199. doi: 10.1039/C0CS00045K
6. [6]
  Y. Chen, X. Wan, G. Long, Acc. Chem. Res. 46(2013) 2645-2655. doi: 10.1021/ar400088c
7. [7]
  C.C. Chueh, C.Z. Li, A.K.Y. Jen, Energy Environ. Sci. 8(2015) 1160-1189. doi: 10.1039/C4EE03824J
8. [8]
  F. Wang, Z.A. Tan, Y. Li, Energy Environ. Sci. 8(2015) 1059-1091. doi: 10.1039/C4EE03802A
9. [9]
  S.D. Collins, N.A. Ran, M.C. Heiber, T.Q. Nguyen, Adv. Energy Mater. 7(2017) 1602242-1602287. doi: 10.1002/aenm.201602242
10. [10]
  W. Zhao, S. Li, H. Yao, et al., J. Am. Chem. Soc. 139(2017) 7148-7151. doi: 10.1021/jacs.7b02677
11. [11]
  J. Wan, X. Xu, G. Zhang, et al., Energy Environ. Sci. 10(2017) 1739-1745. doi: 10.1039/C7EE00805H
12. [12]
  B. Walker, C. Kim, T.Q. Nguyen, Chem. Mater. 23(2010) 470-482.
13. [13]
  J. Roncali, P. Leriche, P. Blanchard, Adv. Mater. 26(2014) 3821-3838. doi: 10.1002/adma.201305999
14. [14]
  X.X. Shen, G.C. Han, Y.P. Yi, Chin. Chem. Lett. 27(2016) 1453-1463. doi: 10.1016/j.cclet.2016.05.030
15. [15]
  B. Kan, M. Li, Q. Zhang, et al., J. Am. Chem. Soc. 137(2015) 3886-3893. doi: 10.1021/jacs.5b00305
16. [16]
  B. Kan, Q. Zhang, M. Li, et al., J. Am. Chem. Soc. 136(2014) 15529-15532. doi: 10.1021/ja509703k
17. [17]
  M. Li, F. Liu, X. Wan, et al., Adv. Mater. 27(2015) 6296-6302. doi: 10.1002/adma.201502645
18. [18]
  Z. Wang, X. Xu, Z. Li, et al., Adv. Electron. Mater. 2(2016) 1600061-1600067. doi: 10.1002/aelm.201600061
19. [19]
  F. Gao, O. Inganas, Phys. Chem. Chem. Phys. 16(2014) 20291-20304. doi: 10.1039/C4CP01814A
20. [20]
  Z. He, C. Zhong, X. Huang, et al., Adv. Mater. 23(2011) 4636-4643. doi: 10.1002/adma.201103006
21. [21]
  S. Sweetnam, K.R. Graham, G.O. Ngongang Ndjawa, et al., J. Am. Chem. Soc. 136(2014) 14078-14088. doi: 10.1021/ja505463r
22. [22]
  X.W. Zhu, K. Lu, H. Li, R.M. Zhou, Z.X. Wei, Chin. Chem. Lett. 27(2016) 1271-1276. doi: 10.1016/j.cclet.2016.06.015
23. [23]
  Y. Lin, X. Zhan, Acc. Chem. Res. 49(2016) 175-183. doi: 10.1021/acs.accounts.5b00363
24. [24]
  Y.S. Chen, X.J. Wan, G.K. Long, Acc. Chem. Res. 46(2013) 2645-2655. doi: 10.1021/ar400088c
25. [25]
  E.E. Havinga, W. Tenhoeve, H. Wynberg, Synthetic Met. 55(1993) 299-306. doi: 10.1016/0379-6779(93)90949-W
26. [26]
  E.E. Havinga, W. Tenhoeve, H. Wynberg, Polym. Bull. 29(1992) 119-126. doi: 10.1007/BF00558045
27. [27]
  A.B. Tamayo, B. Walker, T.Q. Nguyen, J. Mater. Chem. C 112(2008) 11545-11551.
28. [28]
  B. Walker, A.B. Tamayo, X.D. Dang, et al., Adv. Funct. Mater. 19(2009) 3063-3069. doi: 10.1002/adfm.v19:19
29. [29]
  J.D.A. Lin, J. Liu, C. Kim, et al., RSC Adv. 4(2014) 14101-14108. doi: 10.1039/C3RA45662E
30. [30]
  O.P. Lee, A.T. Yiu, P.M. Beaujuge, et al., Adv. Mater. 23(2011) 5359-5363. doi: 10.1002/adma.201103177
31. [31]
  J. Huang, H. Jia, L. Li, et al., Phys. Chem. Chem. Phys. 14(2012) 14238-14242. doi: 10.1039/c2cp42050c
32. [32]
  E. Kozma, D. Kotowski, F. Galeotti, et al., Mater. Chem. Phys. 147(2014) 365-370. doi: 10.1016/j.matchemphys.2014.06.048
33. [33]
  R. Zhou, Q.D. Li, X.C. Li, et al., Dyes Pigm. 101(2014) 51-57. doi: 10.1016/j.dyepig.2013.09.022
34. [34]
  M. Más-Montoya, R.A.J. Janssen, Adv. Funct. Mater. 27(2017) 1605779-1605790. doi: 10.1002/adfm.v27.16
35. [35]
  L. Yuan, Y. Zhao, K. Lu, et al., J. Mater. Chem. C 2(2014) 5842-5849. doi: 10.1039/C4TC00921E
36. [36]
  A. Tang, C. Zhan, J. Yao, E. Zhou, Adv. Mater. 29(2017) 1600013-1600052. doi: 10.1002/adma.v29.2
37. [37]
  K. Schulze, C. Uhrich, R. Schüppel, et al., Adv. Mater. 18(2006) 2872-2875. doi: 10.1002/(ISSN)1521-4095
38. [38]
  Y. Liu, X. Wan, B. Yin, et al., J. Mater. Chem. C 20(2010) 2464-2468. doi: 10.1039/b925048d
39. [39]
  Y. Liu, X. Wan, F. Wang, et al., Adv. Energy Mater. 1(2011) 771-775. doi: 10.1002/aenm.v1.5
40. [40]
  Z. Li, G. He, X. Wan, et al., Adv. Energy Mater. 2(2012) 74-77. doi: 10.1002/aenm.201100572
41. [41]
  G. He, Z. Li, X. Wan, et al., J. Mater. Chem. A 1(2013) 1801-1809. doi: 10.1039/C2TA00496H
42. [42]
  N. Liang, D. Meng, Z. Ma, et al., Adv. Energy Mater. 7(2017) 1601664-1601669. doi: 10.1002/aenm.201601664
43. [43]
  Z. Wang, Z. Li, J. Liu, et al., ACS Appl. Mater. Interfaces 8(2016) 11639-11648. doi: 10.1021/acsami.6b01784
44. [44]
  Y. Lin, L. Ma, Y. Li, et al., Adv. Energy Mater. 3(2013) 1166-1170. doi: 10.1002/aenm.v3.9
45. [45]
  C.E. Song, Y.J. Kim, S.R. Suranagi, et al., ACS Appl. Mater. Interf. 8(2016) 12940-12950. doi: 10.1021/acsami.6b01576
46. [46]
  J. Wang, K. Shi, Y. Suo, et al., J. Mater. Chem. C 4(2016) 3781-3791. doi: 10.1039/C5TC03589A
47. [47]
  K. Gao, L. Li, T. Lai, et al., J. Am. Chem. Soc. 137(2015) 7282-7285. doi: 10.1021/jacs.5b03740
48. [48]
  K. Gao, J. Miao, L. Xiao, et al., Adv. Mater. 28(2016) 4727-4733. doi: 10.1002/adma.v28.23
49. [49]
  T. Liang, L. Xiao, K. Gao, et al., ACS Appl. Mater. Interf. 9(2017) 7131-7138. doi: 10.1021/acsami.6b15241
50. [50]
  J.W. Jung, T.P. Russell, W.H. Jo, Chem. Mater. 27(2015) 4865-4870. doi: 10.1021/acs.chemmater.5b01799
51. [51]
  R. Wu, L. Yin, Y. Li, Sci. China Mater. 59(2016) 371-388.
52. [52]
  Y. Liu, X. Wan, F. Wang, et al., Adv. Mater. 23(2011) 5387-5391. doi: 10.1002/adma.201102790
53. [53]
  C. Cui, X. Guo, J. Min, et al., Adv. Mater. 27(2015) 7469-7475. doi: 10.1002/adma.201503815
54. [54]
  K. Sun, Z. Xiao, S. Lu, et al., Nat. Commun. 6(2015) 6013-6021. doi: 10.1038/ncomms7013
55. [55]
  S. Badgujar, G.Y. Lee, T. Park, et al., Adv. Energy Mater. 6(2016) 1600228-1600236. doi: 10.1002/aenm.201600228
56. [56]
  Z. Zhou, S. Xu, W. Liu, et al., J. Mater. Chem. A 5(2017) 3425-3433. doi: 10.1039/C6TA10559A
57. [57]
  D. Deng, Y. Zhang, L. Yuan, et al., Adv. Energy Mater. 4(2014) 1400538-1400544. doi: 10.1002/aenm.201400538
58. [58]
  D. Deng, Y. Zhang, L. Zhu, et al., Phys. Chem. Chem. Phys.17(2015) 8894-8900. doi: 10.1039/C5CP00042D
59. [59]
  D. Deng, Y. Zhang, J. Zhang, et al., Nat. Commun. 7(2016) 13740-13748. doi: 10.1038/ncomms13740
60. [60]
  J. Zhou, X. Wan, Y. Liu, et al., Chem. Mater. 23(2011) 4666-4668. doi: 10.1021/cm202588h
61. [61]
  W. Ni, M. Li, F. Liu, et al., Chem. Mater. 27(2015) 6077-6084. doi: 10.1021/acs.chemmater.5b02616
62. [62]
  L. Xiao, S. Chen, K. Gao, et al., ACS Appl. Mater. Interf. 8(2016) 30176-30183. doi: 10.1021/acsami.6b09790
63. [63]
  W. Wang, P. Shen, X. Dong, et al., ACS Appl. Mater. Interf. 9(2017) 4614-4625. doi: 10.1021/acsami.6b14114
64. [64]
  X. Zhu, B. Xia, K. Lu, et al., Chem. Mater. 28(2016) 943-950. doi: 10.1021/acs.chemmater.5b04668
65. [65]
  J. Sim, H. Lee, K. Song, et al., J. Mater. Chem. C 4(2016) 3508-3516. doi: 10.1039/C6TC00323K
66. [66]
  C. Cui, W.Y. Wong, Y. Li, Energy Environ. Sci. 7(2014) 2276-2284. doi: 10.1039/C4EE00446A
67. [67]
  S. Shen, P. Jiang, C. He, et al., Chem. Mater. 25(2013) 2274-2281. doi: 10.1021/cm400782q
68. [68]
  J. Zhao, B. Xia, K. Lu, et al., RSC Adv. 6(2016) 60595-60601. doi: 10.1039/C6RA09417A
69. [69]
  J. Min, Y.N. Luponosov, N. Gasparini, et al., J. Mater. Chem. A 3(2015) 22695-22707. doi: 10.1039/C5TA06706E
70. [70]
  C.D. Wessendorf, A. Perez-Rodriguez, J. Hanisch, et al., J. Mater. Chem. A 4(2016) 2571-2580. doi: 10.1039/C5TA07713C
71. [71]
  Y. Sun, G.C. Welch, W.L. Leong, et al., Nat. Mater. 11(2011) 44-48.
72. [72]
  T.S. van der Poll, J.A. Love, T.Q. Nguyen, G.C. Bazan, Adv. Mater. 24(2012) 3646-3649. doi: 10.1002/adma.v24.27
73. [73]
  J.H. Yun, S. Park, J.H. Heo, et al., Chem. Sci. 7(2016) 6649-6661. doi: 10.1039/C6SC02448C
74. [74]
  M. Moon, B. Walker, J. Lee, et al., Adv. Energy Mater. 5(2015) 1402044-1402054. doi: 10.1002/aenm.201402044
75. [75]
  J.A. Love, I. Nagao, Y. Huang, et al., J. Am. Chem. Soc. 136(2014) 3597-3606. doi: 10.1021/ja412473p
76. [76]
  K. Wang, R.Z. Liang, J. Wolf, et al., Adv. Funct. Mater. 26(2016) 7103-7114. doi: 10.1002/adfm.v26.39
77. [77]
  L. Yuan, Y. Zhao, J. Zhang, et al., Adv. Mater. 27(2015) 4229-4233. doi: 10.1002/adma.v27.28
78. [78]
  Y. Huang, W. Wen, S. Mukherjee, et al., Adv. Mater. 26(2014) 4168-4172. doi: 10.1002/adma.v26.24
79. [79]
  C. McDowell, M. Abdelsamie, K. Zhao, et al., Adv. Energy Mater. 5(2015) 1501121-1501129. doi: 10.1002/aenm.201501121
80. [80]
  R.S. Ashraf, B.C. Schroeder, H.A. Bronstein, et al., Adv. Mater. 25(2013) 2029-2034. doi: 10.1002/adma.201300027
81. [81]
  V. Gupta, L.F. Lai, R. Datt, et al., Chem. Commun. 52(2016) 8596-8599. doi: 10.1039/C6CC03998G
82. [82]
  L.Y. Lin, C.W. Lu, W.C. Huang, et al., Org. Lett. 13(2011) 4962-4965. doi: 10.1021/ol2021077
83. [83]
  X. Liu, Y. Sun, B.B. Hsu, et al., J. Am. Chem. Soc. 136(2014) 5697-5708. doi: 10.1021/ja413144u
84. [84]
  J.L. Wang, F. Xiao, J. Yan, et al., Adv. Funct. Mater. 26(2016) 1803-1812. doi: 10.1002/adfm.v26.11
85. [85]
  J.L. Wang, K.K. Liu, J. Yan, et al., J. Am. Chem. Soc. 138(2016) 7687-7697. doi: 10.1021/jacs.6b03495
86. [86]
  L. Yuan, K. Lu, B. Xia, et al., Adv. Mater. 28(2016) 5980-5985. doi: 10.1002/adma.201600512
87. [87]
  H. Bin, Y. Yang, Z.G. Zhang, et al., J. Am. Chem. Soc. 139(2017) 5085-5094. doi: 10.1021/jacs.6b12826
88. [88]
  Z. Zheng, O.M. Awartani, B. Gautam, et al., Adv. Mater. 29(2017) 1604241-1604246. doi: 10.1002/adma.201604241
89. [89]
  Y. Yang, Z.G. Zhang, H. Bin, et al., J. Am. Chem. Soc. 138(2016) 15011-15018. doi: 10.1021/jacs.6b09110
90. [90]
  D. Liu, B. Yang, B. Jang, et al., Energy Environ. Sci. 10(2017) 546-551. doi: 10.1039/C6EE03489F
91. [91]
  F. Zhao, S. Dai, Y. Wu, et al., Adv. Mater. 29(2017) 1700144-1700150. doi: 10.1002/adma.201700144
1. [1]
  Rong-Nan Yi , Wei-Min He . Electron donor-acceptor complex enabled arylation of dithiocarbamate anions with thianthrenium salts under aqueous micellar conditions. Chinese Chemical Letters, 2024, 35(11): 110194-. doi: 10.1016/j.cclet.2024.110194
2. [2]
  Jiawei Li , Cheng Chen , Mingyan Wu . Donor-acceptor type organic cocrystals for deep-red circularly polarized luminescence and two-photon excited emission. Chinese Journal of Structural Chemistry, 2025, 44(3): 100513-100513. doi: 10.1016/j.cjsc.2025.100513
3. [3]
  Ali Dai , Zhiguo Zheng , Liusheng Duan , Jian Wu , Weiming Tan . Small molecule chemical scaffolds in plant growth regulators for the development of agrochemicals. Chinese Chemical Letters, 2025, 36(4): 110462-. doi: 10.1016/j.cclet.2024.110462
4. [4]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
5. [5]
  Kun Zhang , Ni Dan , Dan-Dan Ren , Ruo-Yu Zhang , Xiaoyan Lu , Ya-Pan Wu , Li-Lei Zhang , Hong-Ru Fu , Dong-Sheng Li . A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(3): 100244-100244. doi: 10.1016/j.cjsc.2024.100244
6. [6]
  Aolei Tan , Xiaoxiao Ma . Exploring the functional roles of small-molecule metabolites in disease research: Recent advancements in metabolomics. Chinese Chemical Letters, 2024, 35(8): 109276-. doi: 10.1016/j.cclet.2023.109276
7. [7]
  Brandon Bishop , Shaofeng Huang , Hongxuan Chen , Haijia Yu , Hai Long , Jingshi Shen , Wei Zhang . Artificial transmembrane channel constructed from shape-persistent covalent organic molecular cages capable of ion and small molecule transport. Chinese Chemical Letters, 2024, 35(11): 109966-. doi: 10.1016/j.cclet.2024.109966
8. [8]
  Yunjie Dang , Yanru Feng , Xiao Chen , Chaoxing He , Shujie Wei , Dingyang Liu , Jinlong Qi , Huaxing Zhang , Shaokun Yang , Zhiyun Niu , Bai Xiang . Development of a multi-level pH-responsive lipid nanoplatform for efficient co-delivery of siRNA and small-molecule drugs in tumor treatment. Chinese Chemical Letters, 2024, 35(12): 109660-. doi: 10.1016/j.cclet.2024.109660
9. [9]
  Guixu Pan , Zhiling Xia , Ning Wang , Hejia Sun , Zhaoqi Guo , Yunfeng Li , Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2024.100463
10. [10]
  Jun-Jie Fang , Yun-Peng Xie , Xing Lu . Organooxotin and cobalt/manganese heterometallic nanoclusters exhibiting single-molecule magnetism. Chinese Journal of Structural Chemistry, 2025, 44(4): 100515-100515. doi: 10.1016/j.cjsc.2025.100515
11. [11]
  Jinge Zhu , Ailing Tang , Leyi Tang , Peiqing Cong , Chao Li , Qing Guo , Zongtao Wang , Xiaoru Xu , Jiang Wu , Erjun Zhou . Chlorination of benzyl group on the terminal unit of A₂-A₁-D-A₁-A₂ type nonfullerene acceptor for high-voltage organic solar cells. Chinese Chemical Letters, 2025, 36(1): 110233-. doi: 10.1016/j.cclet.2024.110233
12. [12]
  Jin Wang , Xiaoyan Pan , Junyu Zhang , Qingqing Zhang , Yanchen Li , Weiwei Guo , Jie Zhang . Active molecule-based theranostic agents for tumor vasculature normalization and antitumor efficacy. Chinese Chemical Letters, 2024, 35(8): 109187-. doi: 10.1016/j.cclet.2023.109187
13. [13]
  Siwei Wang , Wei-Lei Zhou , Yong Chen . Cucurbituril and cyclodextrin co-confinement-based multilevel assembly for single-molecule phosphorescence resonance energy transfer behavior. Chinese Chemical Letters, 2024, 35(12): 110261-. doi: 10.1016/j.cclet.2024.110261
14. [14]
  Ying-Yu Zhang , Jia-Qi Luo , Yan Han , Wan-Ying Zhang , Yi Zhang , Hai-Feng Lu , Da-Wei Fu . Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature. Chinese Chemical Letters, 2025, 36(1): 109530-. doi: 10.1016/j.cclet.2024.109530
15. [15]
  Xinyi Luo , Ke Wang , Yingying Xue , Xiaobao Cao , Jianhua Zhou , Jiasi Wang . Digital PCR-free technologies for absolute quantitation of nucleic acids at single-molecule level. Chinese Chemical Letters, 2025, 36(2): 109924-. doi: 10.1016/j.cclet.2024.109924
16. [16]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
17. [17]
  Wenya Jiang , Jianyu Wei , Kuan-Guan Liu . Atomically precise superatomic silver nanoclusters stabilized by O-donor ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100371-100371. doi: 10.1016/j.cjsc.2024.100371
18. [18]
  Chengcheng Xie , Chengyi Xiao , Hongshuo Niu , Guitao Feng , Weiwei Li . Mesoporous organic solar cells. Chinese Chemical Letters, 2024, 35(11): 109849-. doi: 10.1016/j.cclet.2024.109849
19. [19]
  Pingfan Zhang , Shihuan Hong , Ning Song , Zhonghui Han , Fei Ge , Gang Dai , Hongjun Dong , Chunmei Li . Alloy as advanced catalysts for electrocatalysis: From materials design to applications. Chinese Chemical Letters, 2024, 35(6): 109073-. doi: 10.1016/j.cclet.2023.109073
20. [20]
  Xinyu Yu , Fei Wu , Xianglang Sun , Linna Zhu , Baoyu Xia , Zhong'an Li . Low-cost dopant-free fluoranthene-based branched hole transporting materials for efficient and stable n-i-p perovskite solar cells. Chinese Chemical Letters, 2024, 35(10): 109821-. doi: 10.1016/j.cclet.2024.109821

Get Citation

PDF

XML

Metrics

PDF Downloads(18)
Abstract views(1808)
HTML views(21)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142