Citation: Tang Baolei, Zhang Zuolun, Liu Huapeng, Zhang Hongyu. Amplified spontaneous emission, optical waveguide and polarized emission based on 2, 5-diaminoterephthalates[J]. Chinese Chemical Letters, ;2017, 28(11): 2129-2132. doi: 10.1016/j.cclet.2017.08.045 shu

Amplified spontaneous emission, optical waveguide and polarized emission based on 2, 5-diaminoterephthalates

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China

Corresponding author: Zhang Zuolun, zuolunzhang@jlu.edu.cn Zhang Hongyu, hongyuzhang@jlu.edu.cn
Received Date: 26 June 2017
Revised Date: 23 August 2017
Accepted Date: 23 August 2017
Available Online: 12 November 2017

Figures(6)

A series of 2, 5-diaminoterephthalates with a simple structure were synthesized through one-step reaction, and their bar-shaped single crystals with a large size and a smooth surface have been obtained via the solvent-evaporation method. These crystals exhibit bright emission with fluorescence quantum yields higher than 0.2. They display the waveguide property, and low optical loss coefficients for waveguide have been determined for the crystal of one compound. In addition, the crystal can cause linear polarization of the light emitted from it, with a high polarization contrast of 0.70. Most importantly, these crystals can realize amplified spontaneous emission (ASE), including the red ASE, with appreciable energy thresholds of 72-198 kW/cm² and high gain coefficients, which suggests the potential of these crystals for the application in organic solid-state lasers.
- 2, 5-Diaminoterephthalates,
- Waveguide,
- Polarization,
- Amplified spontaneous emission,
- Laser
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