Citation: Ma Jiahui, Wang Tianren, Liu Caixia, Li Huanrong. Tunable white-light emission of lanthanide(Ⅲ) hybrid material based on hectorite[J]. Chinese Chemical Letters, ;2018, 29(2): 321-324. doi: 10.1016/j.cclet.2017.08.010 shu

Tunable white-light emission of lanthanide(Ⅲ) hybrid material based on hectorite

Hebei Provincial Key Lab of Green Chemical Technology and High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

Corresponding author: Li Huanrong, lihuanrong@hebut.edu.cn
Received Date: 26 April 2017
Revised Date: 16 May 2017
Accepted Date: 5 August 2017
Available Online: 12 February 2017

Figures(5)

In this work, we present novel trivalent lanthanide ions (Ln³⁺)-based luminescent hybrid materials, in which the organic ligands are covalently grafted on the hectorite templates and the Ln³⁺ ions can be well immobilized by the ligands through coordination bond. The hybrid materials exhibit tunable emission colors by varying the molar ratio of Eu³⁺ to Tb³⁺, and the one with Eu³⁺:Tb³⁺=1:1 exhibits excellent coordinate of (0.327, 0.328) located in the "white region" of the CIE 1931 chromaticity diagram (under 300 nm UV illumination). These properties make the hybrid composites suitable for fabricating optoelectronic devices such as full-color displays and white LED.
- Hectorite,
- Lanthanide,
- Covalent bond,
- Luminescence,
- White light
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