Citation: Zhao Fang, Xin Li, Zhang Yingying, Jia Xuefeng. Monodentate phosphorus-coordinated palladium(Ⅱ) complexes as new catalyst for Mizoroki-Heck reaction of aryl halides with electron-deficient olefins[J]. Chinese Chemical Letters, ;2018, 29(3): 493-496. doi: 10.1016/j.cclet.2017.08.004 shu

Monodentate phosphorus-coordinated palladium(Ⅱ) complexes as new catalyst for Mizoroki-Heck reaction of aryl halides with electron-deficient olefins

Zhao Fang ^a,1 ,
Xin Li ^a,1 ,
Zhang Yingying ^b ,
Jia Xuefeng ^a,b,,

a.
School of Chemical and Material Science, Shanxi Normal University, Linfen 041004, China
b.
Department of Chemistry, Modern College of Arts and Sciences, Shanxi Normal University, Linfen 041000, China

Corresponding author: Jia Xuefeng, jxfliu@163.com

Received Date: 8 May 2017
Revised Date: 11 July 2017
Accepted Date: 2 August 2017
Available Online: 3 March 2017

Figures(1)

Four novel palladium(Ⅱ) complexes coordinated by phosphorus atoms from both 3, 5-disubstituted-1H-1, 2, 4-diazaphospholes in monodentate fashion were developed as efficient catalyst for the MizorokiHeck reaction of aryl halides with electron-deficient olefins. The coupling reaction of aryl halide bearig different functional groups with olefin derivatives took place and the corresponding products were isolated in good to excellent yields under optimal conditions. The procedure exhibits good functional group tolerance and wide substrate scope. This Mizoroki-Heck reaction was further achieved using Pd(OAc)₂ and 3, 5-di-isopropyl-1H-1, 2, 4-diazaphospholes as combined catalyst, which provide the convenient and alternative method in organic synthesis
- Palladium(Ⅱ) complexes,
- Monodentate phosphine ligands,
- Mizoroki-Heck reaction,
- Aryl halides,
- Olefins
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