Citation: Wang Xian-Long, Li Hong-Jie, Yan Jie. Iodine-mediated regioselective hydroxyselenenylation of alkenes: Facile access to β-hydroxy selenides[J]. Chinese Chemical Letters, ;2018, 29(3): 479-481. doi: 10.1016/j.cclet.2017.06.023 shu

Iodine-mediated regioselective hydroxyselenenylation of alkenes: Facile access to β-hydroxy selenides

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310015, China

Corresponding author: Yan Jie, jieyan87@zjut.edu.cn
Received Date: 2 May 2017
Revised Date: 28 May 2017
Accepted Date: 23 June 2017
Available Online: 27 March 2017

Figures(1)

In the presence of molecular iodine, the reaction of alkenes with diselenides proceeds efficiently under air and at room temperature in mixed solvent MeCN/H₂O, which affording β-hydroxy selenides with high regioselectivity and in good to excellent yields. This iodine-mediated vicinal difunctionalization of alkenes requires mild reaction conditions and is a simple procedure, which extends the synthetic application of molecular iodine in organic synthesis.
- β-Hydroxy selenide,
- Hydroxyselenenylation,
- Diselenide,
- Alkene,
- I₂
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