Citation: Li Huanmin, Xie Xu-Ming. Polyolefin-functionalized graphene oxide and its GO/HDPE nanocomposite with excellent mechanical properties[J]. Chinese Chemical Letters, ;2018, 29(1): 161-165. doi: 10.1016/j.cclet.2017.06.001 shu

Polyolefin-functionalized graphene oxide and its GO/HDPE nanocomposite with excellent mechanical properties

Li Huanmin ,
Xie Xu-Ming ^,

Laboratory of Advanced Materials(MOE), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Xie Xu-Ming, xxm-dce@mail.tsinghua.edu.cn
Received Date: 28 March 2017
Revised Date: 24 April 2017
Accepted Date: 2 June 2017
Available Online: 3 January 2017

Figures(5)

To prepare GO/Polyolefin nanocomposites with enhanced mechanical, electrical, or thermal properties is still a challenge due to the poor interfacial adhesion between GO and non-polar polyolefins. In this study, we report an effective strategy for the polyolefin-functionalized graphene oxide (fGO) using two-step methods GO was firstly modified by using glycidyl methacrylate (GMA) and styrene (St) dual monomers grafting method, thus GO-g-(GMA-co-St) with numerous epoxide groups is obtained. Then through the reaction between the epoxide group of GMA and anhydride group of maleic anhydrides (MAH) of the prepared HDPE-g-(MAH-co-St), GO-g-HDPE-g-(MAH-co-St) could be obtained. The successful preparation of the GO-g-HDPE-g-(MAH-co-St) was confirmed by AFM, TEM, FTIR, XRD, DSC, and TGA characterization. The results show the grafting ratios of the poly(GMA-co-St) and HDPE-g-(MAH-co-St) being up to 50.4 wt% and 70.4 wt%, respectively. The functionalized GO shows homogeneous dispersion in the nanocomposites with HDPE, and the stress at break and strain at break of the nanocomposite is increased by 28.7% and 130% respectively with only 0.2 wt% fGO loading. The approach of the polyolefin-functionalized GO paves a new way to develop not only polyolefin/graphene nanocomposites but also excellent nanocomposites of polyolefin/engineering plastic blends with graphene.
- Graphene oxide,
- Polyolefin-functionalized,
- Homogeneous dispersion
1. [1]
  D.R. Dreyer, S. Park, C.W. Bielawski, et al., Chem. Soc. Rev. 39(2010) 228-240. doi: 10.1039/B917103G
2. [2]
  J.R. Potts, D.R. Dreyer, C.W. Bielawski, et al., Polymer 52(2011) 5-25. doi: 10.1016/j.polymer.2010.11.042
3. [3]
  X.Y. Qi, C.L. Tan, J. Wei, et al., Nanoscale 5(2013) 1440-1451. doi: 10.1039/c2nr33145d
4. [4]
  Y.Q. Sun, G.Q. Shi, J. Polym. Sci. Part B:Polym. Phys. 51(2013) 231-253. doi: 10.1002/polb.23226
5. [5]
  X. Huang, X. Qi, F. Boey, H. Zhang, Chem. Soc. Rev. 41(2012) 666-686. doi: 10.1039/C1CS15078B
6. [6]
  X. Zhao, Q. Zhang, D. Chen, et al., Macromolecules 43(2010) 2357-2363. doi: 10.1021/ma902862u
7. [7]
  C. Lin, Y.T. Liu, X.M. Xie, Aust. J. Chem. 67(2014) 121-126. doi: 10.1071/CH13339
8. [8]
  J.R. Potts, S.H. Lee, T.M. Alam, et al., Carbon 49(2011) 2615-2623. doi: 10.1016/j.carbon.2011.02.023
9. [9]
  Y. Yang, C.E. He, W. Tang, et al., J. Mater. Chem. A 2(2014) 20038-20047. doi: 10.1039/C4TA04543B
10. [10]
  R. Rafiq, D. Cai, J. Jin, et al., Carbon 48(2010) 4309-4314. doi: 10.1016/j.carbon.2010.07.043
11. [11]
  Z. Xu, C. Gao, Macromolecules 43(2010) 6716-6723. doi: 10.1021/ma1009337
12. [12]
  H. Kim, Y. Miura, C.W. Macosko, Chem. Mater. 22(2010) 3441-3450. doi: 10.1021/cm100477v
13. [13]
  K. Nawaz, U. Khan, N. Ul-Haq, et al., Carbon 50(2012) 4489-4494. doi: 10.1016/j.carbon.2012.05.029
14. [14]
  T. Kuila, S. Bose, C.E. Hong, et al., Carbon 49(2011) 1033-1037. doi: 10.1016/j.carbon.2010.10.031
15. [15]
  Y. Lin, J. Jin, M. Song, J. Mater. Chem. 21(2011) 3455-3461. doi: 10.1039/C0JM01859G
16. [16]
  H. Kim, S. Kobayashi, M.A. AbdurRahim, et al., Polymer 52(2011) 1837-1846. doi: 10.1016/j.polymer.2011.02.017
17. [17]
  Y. Li, Polymer 52(2011) 2310-2318. doi: 10.1016/j.polymer.2011.03.025
18. [18]
  A.A. Vasileiou, M. Kontopoulou, A. Docoslis, ACS Appl. Mater. Interfaces 6(2014) 1916-1925. doi: 10.1021/am404979g
19. [19]
  Y. Huang, Y. Qin, Y. Zhou, et al., Chem. Mater. 22(2010) 4096-4102. doi: 10.1021/cm100998e
20. [20]
  M.C. Hsiao, S.H. Liao, Y.F. Lin, et al., Nanoscale 3(2011) 1516-1522. doi: 10.1039/c0nr00981d
21. [21]
  P. Song, Z. Cao, Y. Cai, et al., Polymer 52(2011) 4001-4010. doi: 10.1016/j.polymer.2011.06.045
22. [22]
  Y. Cao, J. Feng, P. Wu, J. Mater. Chem. 22(2012) 14997-15005. doi: 10.1039/c2jm31477k
23. [23]
  B. Yuan, C. Bao, L. Song, et al., Chem. Eng. J. 237(2014) 411-420. doi: 10.1016/j.cej.2013.10.030
24. [24]
  X. Yang, T. Mei, J. Yang, et al., Appl. Surf. Sci. 305(2014) 725-731. doi: 10.1016/j.apsusc.2014.03.184
25. [25]
  X. Yang, X. Wang, J. Yang, et al., Chem. Phys. Lett. 570(2013) 125-131. doi: 10.1016/j.cplett.2013.03.069
26. [26]
  W.S. Hummers, R.E. Offeman, J. Am. Chem. Soc. 80(1958) 1339. doi: 10.1021/ja01539a017
27. [27]
  Y. Li, X.M. Xie, B.H. Guo, Polymer 42(2001) 3419-3425. doi: 10.1016/S0032-3861(00)00767-9
28. [28]
  X.M. Xie, Y. Li, J. Zhang, et al., Acta Polym. Sin. 1(2002) 7-12.
29. [29]
  Y. Li, Y. Li, X.M. Xie, Acta Polym. Sin. 4(2011) 347-353.
30. [30]
  S. Stankovich, R.D. Piner, S.T. Nguyen, et al., Carbon 44(2006) 3342-3347. doi: 10.1016/j.carbon.2006.06.004
31. [31]
  L. Kan, Z. Xu, C. Gao, Macromolecules 44(2010) 444-452.
32. [32]
  H. Lee, K. Neville, Handbook of Epoxy Resins, McGraw-Hill, New York, 1967.
33. [33]
  X.M. Xie, N.H. Chen, B.H. Guo, et al., Polym. Int. 49(2000) 1677-1683. doi: 10.1002/(ISSN)1097-0126
34. [34]
  J.L. Li, X.M. Xie, Polymer 53(2012) 2197-2204. doi: 10.1016/j.polymer.2012.03.035
35. [35]
  S. Cheng, X. Chen, Y.G. Hsuan, et al., Macromolecules 45(2012) 993-1000. doi: 10.1021/ma2021453
36. [36]
  P.Q. Yu, X.M. Xie, Z. Wang, et al., Polymer 47(2006) 1460-1464. doi: 10.1016/j.polymer.2005.12.059
37. [37]
  F. Zhang, X.M. Xie, J. Yuan, et al., Acta Polym. Sin. 4(2011) 354-359.
38. [38]
  P.Q. Yu, L.T. Yan, N. Chen, et al., Polymer 53(2012) 4727-4736. doi: 10.1016/j.polymer.2012.08.038
39. [39]
  N. Chen, L. T. Yan, X.M. Xie, Macromolecules 46(2013) 3544-3553. doi: 10.1021/ma4005692
1. [1]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102
2. [2]
  Yuanyi Zhou , Ke Ma , Jinfeng Liu , Zirun Zheng , Bo Hu , Yu Meng , Zhizhong Li , Mingshan Zhu . Is reactive oxygen species the only way for cancer inhibition over single atom nanomedicine? Autophagy regulation also works. Chinese Chemical Letters, 2024, 35(6): 109056-. doi: 10.1016/j.cclet.2023.109056
3. [3]
  Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
4. [4]
  Yihong Li , Zhong Qiu , Lei Huang , Shenghui Shen , Ping Liu , Haomiao Zhang , Feng Cao , Xinping He , Jun Zhang , Yang Xia , Xinqi Liang , Chen Wang , Wangjun Wan , Yongqi Zhang , Minghua Chen , Wenkui Zhang , Hui Huang , Yongping Gan , Xinhui Xia . Plasma enhanced reduction method for synthesis of reduced graphene oxide fiber/Si anode with improved performance. Chinese Chemical Letters, 2024, 35(11): 109510-. doi: 10.1016/j.cclet.2024.109510
5. [5]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
6. [6]
  Manman Ou , Yunjian Zhu , Jiahao Liu , Zhaoxuan Liu , Jianjun Wang , Jun Sun , Chuanxiang Qin , Lixing Dai . Polyvinyl alcohol fiber with enhanced strength and modulus and intense cyan fluorescence based on covalently functionalized graphene quantum dots. Chinese Chemical Letters, 2025, 36(2): 110510-. doi: 10.1016/j.cclet.2024.110510
7. [7]
  Yin-Hang Chai , Li-Long Dang . New structural breakthrough and topological transformation of homogeneous metalla[4]catenane compounds. Chinese Journal of Structural Chemistry, 2024, 43(10): 100322-100322. doi: 10.1016/j.cjsc.2024.100322
8. [8]
  Hao-Cong Li , Ming Zhang , Qiyan Lv , Kai Sun , Xiao-Lan Chen , Lingbo Qu , Bing Yu . Homogeneous catalysis and heterogeneous separation: Ionic liquids as recyclable photocatalysts for hydroacylation of olefins. Chinese Chemical Letters, 2025, 36(2): 110579-. doi: 10.1016/j.cclet.2024.110579
9. [9]
  Guilong Li , Wenbo Ma , Jialing Zhou , Caiqin Wu , Chenling Yao , Huan Zeng , Jian Wang . A composite hydrogel with porous and homogeneous structure for efficient osmotic energy conversion. Chinese Chemical Letters, 2025, 36(2): 110449-. doi: 10.1016/j.cclet.2024.110449
10. [10]
  Jingqi Xin , Shupeng Han , Meichen Zheng , Chenfeng Xu , Zhongxi Huang , Bin Wang , Changmin Yu , Feifei An , Yu Ren . A nitroreductase-responsive nanoprobe with homogeneous composition and high loading for preoperative non-invasive tumor imaging and intraoperative guidance. Chinese Chemical Letters, 2024, 35(7): 109165-. doi: 10.1016/j.cclet.2023.109165
11. [11]
  Wenjing Dai , Lan Luo , Zhen Yin . Interface reconstruction of hybrid oxide electrocatalysts for seawater oxidation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100442-100442. doi: 10.1016/j.cjsc.2024.100442
12. [12]
  Zili Ma , Zeyu Li , Jun Lv . Shortening the formation time of oxide thin film photoelectrodes from hours to seconds. Chinese Journal of Structural Chemistry, 2025, 44(4): 100450-100450. doi: 10.1016/j.cjsc.2024.100450
13. [13]
  Tian Cao , Xuyin Ding , Qiwen Peng , Min Zhang , Guoyue Shi . Intelligent laser-induced graphene sensor for multiplex probing catechol isomers. Chinese Chemical Letters, 2024, 35(7): 109238-. doi: 10.1016/j.cclet.2023.109238
14. [14]
  Rui Liu , Jinbo Pang , Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329
15. [15]
  Zhuwen Wei , Jiayan Chen , Congzhen Xie , Yang Chen , Shifa Zhu . Divergent de novo construction of α-functionalized pyrrole derivatives via coarctate reaction. Chinese Chemical Letters, 2024, 35(12): 109677-. doi: 10.1016/j.cclet.2024.109677
16. [16]
  Xinyi Hu , Riguang Zhang , Zhao Jiang . Depositing the PtNi nanoparticles on niobium oxide to enhance the activity and CO-tolerance for alkaline methanol electrooxidation. Chinese Journal of Structural Chemistry, 2023, 42(11): 100157-100157. doi: 10.1016/j.cjsc.2023.100157
17. [17]
  Chaozheng He , Jia Wang , Ling Fu , Wei Wei . Nitric oxide assists nitrogen reduction reaction on 2D MBene: A theoretical study. Chinese Chemical Letters, 2024, 35(5): 109037-. doi: 10.1016/j.cclet.2023.109037
18. [18]
  Dong Cheng , Youyou Feng , Bingxi Feng , Ke Wang , Guoxin Song , Gen Wang , Xiaoli Cheng , Yonghui Deng , Jing Wei . Polyphenol-mediated interfacial deposition strategy for supported manganese oxide catalysts with excellent pollutant degradation performance. Chinese Chemical Letters, 2024, 35(5): 108623-. doi: 10.1016/j.cclet.2023.108623
19. [19]
  Jiangping Chen , Hongju Ren , Kai Wu , Huihuang Fang , Chongqi Chen , Li Lin , Yu Luo , Lilong Jiang . Boosting hydrogen production of ammonia decomposition via the construction of metal-oxide interfaces. Chinese Journal of Structural Chemistry, 2024, 43(2): 100236-100236. doi: 10.1016/j.cjsc.2024.100236
20. [20]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(752)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142