Citation: Ni Xiao-Lei, Liu Jing, Liu Ying-Ya, Leus Karen, Depauw Hannes, Wang An-Jie, Voort Pascal Van Der, Zhang Jian, Hu Yong-Kang. Synthesis, characterization and catalytic performance of Mo based metal-organic frameworks in the epoxidation of propylene by cumene hydroperoxide[J]. Chinese Chemical Letters, ;2017, 28(5): 1057-1061. doi: 10.1016/j.cclet.2017.01.020 shu

Synthesis, characterization and catalytic performance of Mo based metal-organic frameworks in the epoxidation of propylene by cumene hydroperoxide

a.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China
b.
Department of Inorganic and Physical Chemistry, COMOC-Center for Ordered Materials, Organometallics and Catalysis, Ghent University, Krijgslaan 281-S3, 9000 Ghent, Belgium
c.
Liaoning Key Laboratory of Petrochemical Technology and Equipments, Dalian 116024, China
d.
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Corresponding author: Liu Jing, liujing@dlut.edu.cn
Received Date: 31 August 2016
Revised Date: 2 December 2017
Accepted Date: 18 January 2017
Available Online: 22 May 2017

Figures(4)

Two types of Mo containing metal-organic frameworks, denoted as Mo@COMOC-4 and PMA@MIL-101 (Cr), were synthesized respectively by a post-synthetic modification and a ship-in-bottle approach. The catalytic performance of both compounds in the epoxidation of propylene using cumene hydroperoxide (CHP) as oxidant was compared with MoO₃@SiO₂. A higher conversion (46.2%) and efficiency (87.4%) of CHP was observed for Mo@COMOC-4, whereas the heteropoly acids supported MIL-101 resulted in the decomposition of CHP due to its strong acidic character. Regenerability tests demonstrated that Mo@COMOC-4 could be reused for multiple runs without significant loss in both activity and stability. © 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
- Metal-organic framework,
- Molybdenum,
- Cumene hydroperoxide,
- Propylene epoxidation
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1.
沈阳化工大学材料科学与工程学院沈阳 110142