Citation: Meng Fan-Qiang, Feng Xiu-Juan, Wang Wan-Hui, Bao Ming. Synthesis of 5-vinyl-2-norbornene through Diels-Alder reaction of cyclopentadiene with 1, 3-butadiene in supercritical carbon dioxide[J]. Chinese Chemical Letters, ;2017, 28(4): 900-904. doi: 10.1016/j.cclet.2016.12.018 shu

Synthesis of 5-vinyl-2-norbornene through Diels-Alder reaction of cyclopentadiene with 1, 3-butadiene in supercritical carbon dioxide

Meng Fan-Qiang ^a,b ,
Feng Xiu-Juan ^a,,, ,
Wang Wan-Hui ^a,b ,
Bao Ming ^a,b,,,

a.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China
b.
School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin 124221, China

Corresponding author: Feng Xiu-Juan, fengxiujuan@dlut.edu.cn Bao Ming, mingbao@dlut.edu.cn

Received Date: 24 October 2016
Revised Date: 28 November 2016
Accepted Date: 28 November 2016
Available Online: 16 April 2016

Figures(3)

An efficient method for the synthesis of 5-vinyl-2-norbornene from cyclopentadiene and 1, 3-butadiene was developed.The Diels-Alder reaction of cyclopentadiene with 1, 3-butadiene proceeded smoothly in supercritical carbon dioxide in the absence of any polymerization inhibitor to produce the corresponding 5-vinyl-2-norbornene in satisfactory yield with high selectivity.
- 5-Vinyl-2-norbornene,
- Diels-Alder reaction,
- Cyclopentadiene,
- 1, 3-Butadiene,
- Supercritical carbon dioxide
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