Citation: Tian Zheng-Fang, Xie Ming-Jiang, Shen Yu, Wang Yong-Zheng, Guo Xue-Feng. Fabrication of sulfonated mesoporous carbon by evaporation induced self-assembly/carbonization approach and its supercapacitive properties[J]. Chinese Chemical Letters, ;2017, 28(4): 863-867. doi: 10.1016/j.cclet.2016.12.004 shu

Fabrication of sulfonated mesoporous carbon by evaporation induced self-assembly/carbonization approach and its supercapacitive properties

a.
Hubei Key Laboratory for Processing and Application of Catalytic Materials, Huanggang Normal University, Huanggang 438000, China
b.
Key Lab of Mesoscopic Chemistry MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: Xie Ming-Jiang, xiemingjiang@hotmail.com Guo Xue-Feng, guoxf@nju.edu.cn
Received Date: 31 October 2016
Revised Date: 20 November 2016
Accepted Date: 29 November 2016
Available Online: 10 April 2016

Figures(4)

Synthesis of functionalized mesoporous carbon by an easy-accessed method is of great importance towards its practical applications.Herein, an evaporation induced self-assembly/carbonization (EISAC) method was developed and applied to the synthesis of sulfonic acid group functionalized mesoporous carbon (SMC).The final mesoporous carbon obtained by EISAC method possesses wormlike mesoporous structure, uniform pore size (3.6 nm), large surface area of 735 m²/g, graphitic pore walls and rich sulfonic acid group.Moreover, the resultant mesoporous carbon achieves a superior electrochemical capacitive performances (216 F/g) to phenolic resin derived mesoporous carbon (OMC, 152 F/g) and commercial activated carbon (AC, 119 F/g).
- Sucrose,
- Mesoporous carbon,
- Self-assembly/carbonization,
- Sulfonic functionalities,
- Supercapacitor
1. [1]
  M. J. Xie, H. H. Dong, D. D. Zhang, X. F. Guo, W. P. Ding, Simple synthesis of highly ordered mesoporous carbon by self-assembly of phenol-formaldehyde and block copolymers under designed aqueous basic/acidic conditions, Carbon 49 (2011)2459-2464.
2. [2]
  Fang Y.Y., Dai W., Chen L., Ma N. Facile synthesis of ordered mesoporous carbon with finger citron residue as carbon precursor[J]. Mater.Lett., 2016,174:246-248. doi: 10.1016/j.matlet.2016.02.086
3. [3]
  M. J. Xie, Y. F. Xia, J. Y. Liang, L. H. Chen, X. F. Guo, Ordered nitrogen doped mesoporous carbon assembled under aqueous acidic conditions and its electrochemical capacitive properties, Microporous Mesoporous Mater. 197 (2014)237-243.
4. [4]
  Liu M.X., Deng X.X., Zhu D.Z.. Magnetically separated and N, S co-doped mesoporous carbon microspheres for the removal of mercury ions[J]. Chin. Chem.Lett., 2016,27:795-800. doi: 10.1016/j.cclet.2016.01.038
5. [5]
  Zhang H., Liu D.L., Zeng L.L., Li M. β-Cyclodextrin assisted one-pot synthesis of mesoporous magnetic Fe3O4@C and their excellent performance for the removal of Cr (Ⅵ) from aqueous solutions[J]. Chin.Chem.Lett., 2013,24:341-343. doi: 10.1016/j.cclet.2013.02.007
6. [6]
  X. J. Lu, H. Dou, X. G. Zhang, Mesoporous carbon nanospheres inserting into graphene sheets for flexible supercapacitor film electrode, Mater. Lett. 178 (2016)304-307.
7. [7]
  Xie M.J., Fang K., Shen Y.. Catalytic hydroxylation enables phenol to efficient assembly of ordered mesoporous carbon under highly acidic conditions[J]. Microporous Mesoporous Mater., 2016,223:114-120. doi: 10.1016/j.micromeso.2015.10.042
8. [8]
  Cai J.J., Kong L.B., Zhang J., Luo Y.C., Kang L. A novel polyaniline/mesoporous carbon nano-composite electrode for asymmetric supercapacitor[J]. Chin.Chem. Lett., 2010,21:1509-1512. doi: 10.1016/j.cclet.2010.07.003
9. [9]
  Liu M.X., Gan L.H., Xiong W.. Partially graphitic micro-and mesoporous carbon microspheres for supercapacitors[J]. Chin.Chem.Lett., 2013,24:1037-1040. doi: 10.1016/j.cclet.2013.07.013
10. [10]
  Li Z.H., Li L.Q., Zhu H.P., Liao H.Y., Zhang H.Y. Pore size control of porous carbons using novel silica-based copolymer template and their application in supercapacitor[J]. Mater.Lett., 2016,172:179-183. doi: 10.1016/j.matlet.2016.02.109
11. [11]
  Chen A.B., Yu Y.F., Li Y.T., Li Y.Q., Jia M.L. Solid-state grinding synthesis of ordered mesoporous MgO/carbon spheres composites for CO₂ capture[J]. Mater. Lett., 2016,164:520-523. doi: 10.1016/j.matlet.2015.11.043
12. [12]
  F.Rodríguez , Jaroniec M., B.L.López , Wickramaratne N.P. Aqueous synthesis of bimodal mesoporous carbons and carbon-silica mesostructures under basic conditions[J]. Microporous Mesoporous Mater., 2016,226:299-308. doi: 10.1016/j.micromeso.2016.02.008
13. [13]
  Dong X.Q., Jiang Y., Shan W.B., Zhang M.H. A novel highly ordered mesoporous carbon-based solid acid for synthesis of bisphenol-A[J]. RSC Adv., 2016,6:17118-17124. doi: 10.1039/C5RA24966J
14. [14]
  Liu Y.R., Zhang J. Influence of pore symmetries on the supercapacitive performance of mesoporous carbons co-templated by F127 and PDMS-PEO[J]. Microporous Mesoporous Mater., 2015,206:81-85. doi: 10.1016/j.micromeso.2014.12.020
15. [15]
  Ding S.L., Zheng S.J., Xie M.J.. One-pot synthesis of boron-doped mesoporous carbon with boric acid as a multifunction reagent[J]. Microporous Mesoporous Mater., 2011,142:609-613. doi: 10.1016/j.micromeso.2011.01.003
16. [16]
  Cazetta A.L., Martins A.C., Pezoti O.. Synthesis and application of N-S-doped mesoporous carbon obtained from nanocasting method using bone char as heteroatom precursor and template[J]. Chem.Eng.J., 2016,300:54-63. doi: 10.1016/j.cej.2016.04.124
17. [17]
  G. A. Ferrero, A. B. Fuertes, M. Sevilla, M. M. Titirici, Efficient metal-free N-doped mesoporous carbon catalysts for ORR by a template-free approach, Carbon 106 (2016)179-187.
18. [18]
  Fan J., Boettcher S.W., Stucky G.D. Nanoparticle assembly of ordered multicomponent mesostructured metal oxides via a versatile sol-gel process[J]. Chem.Mater., 2006,18:6391-6396. doi: 10.1021/cm062359d
19. [19]
  Zhang C.W., Xu L.B., Chen J.F. High loading Pt nanoparticles on ordered mesoporous carbon sphere arrays for highly active methanol electro-oxidation[J]. Chin.Chem.Lett., 2016,27:832-836. doi: 10.1016/j.cclet.2016.02.025
20. [20]
  Xie M.J., Yang J., Liang J.Y., Guo X.F., Ding W.P. In situ hydrothermal deposition as an efficient catalyst supporting method towards low-temperature graphitization of amorphous carbon[J]. Carbon, 2014,77:215-225. doi: 10.1016/j.carbon.2014.05.024
21. [21]
  Qian X.F., Wan Y., Wen Y.L.. Synthesis of ordered mesoporous crystalline carbon-anatase composites with high titania contents[J]. J.Colloid Interface Sci., 2008,328:367-373. doi: 10.1016/j.jcis.2008.08.067
22. [22]
  Xing R., Liu Y.M., Wang Y.. Active solid acid catalysts prepared by sulfonation of carbonization-controlled mesoporous carbon materials[J]. Microporous Mesoporous Mater., 2007,105:41-48. doi: 10.1016/j.micromeso.2007.06.043
23. [23]
  Xie M.J., Duan S.Y., Shen Y.. In-situ-grown Mg (OH)₂-derived hybrid a-Ni (OH)₂ for highly stable supercapacitor[J]. ACS Energy Lett., 2016,1:814-819. doi: 10.1021/acsenergylett.6b00258
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1.
沈阳化工大学材料科学与工程学院沈阳 110142