Citation: Chang Yang, Shen Chen, Li Pin-Yi, Fang Lei, Tong Zai-Zai, Min Min, Xiong Chun-Hua. Optimization of polyacrylonitrile-cysteine resin synthesis and its selective removal of Cu (II) in aqueous solutions[J]. Chinese Chemical Letters, ;2017, 28(2): 319-323. doi: 10.1016/j.cclet.2016.08.003 shu

Optimization of polyacrylonitrile-cysteine resin synthesis and its selective removal of Cu (II) in aqueous solutions

Chang Yang ^a ,
Shen Chen ^a ,
Li Pin-Yi ^a ,
Fang Lei ^b ,
Tong Zai-Zai ^c,d ,
Min Min ^a ,
Xiong Chun-Hua ^a,,

a.
Department of Applied Chemistry, Zhejiang Gongshang University, Hangzhou 310012, China
b.
Department of Food Science and Human Nutrition, University of Florida, Bldg 475 Newell Drive, FL 32611, USA
c.
Zhejiang Provincial Key Laboratory of Fiber Materials and Manufacturing Technology, Hangzhou 310018, China
d.
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China

Corresponding author: Xiong Chun-Hua, xiongch@163.com
Received Date: 23 May 2016
Revised Date: 16 July 2016
Accepted Date: 22 August 2016
Available Online: 3 February 2016

Figures(5)

Polyacrylonitrile beads (PAN) cysteine (CS) was synthesized from polyacrylonitrile beads (PAN) and cysteine (CS). The content of the functional group and the percentage conversion of the functional group of PAN-CS prepared under the optimum condition using response surface methodology (RSM) for the first attempt were 3.22 mmol/g and 35.78%. The structure was characterized by FT-IR and elemental analysis. The adsorption properties of the resin for Cu (II) were investigated by batch and column experiments. Batch adsorption results suggested that PAN-CS had higher adsorption capability for Cu (II) than other metal ions and maximum saturated adsorption capacity was 184.7 mg/g. The resin and its metal complexes were studied by FT-IR. Furthermore, the resin can be eluted easily using 1 mol/L HCl. PAN-CS can provide a potential application for selective removal of copper from waste solution.
- Chelating resin,
- Cysteine,
- RSM,
- Adsorption,
- Cu (II)
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