Citation: Wang Tian-Nan, Yang Guang, Wu Li-Bin, Chen Guo-Song. Self-assembly of supra-amphiphile of azobenzenegalactopyranoside based on dynamic covalent bond and its dual responses[J]. Chinese Chemical Letters, ;2016, 27(12): 1740-1744. doi: 10.1016/j.cclet.2016.05.009 shu

Self-assembly of supra-amphiphile of azobenzenegalactopyranoside based on dynamic covalent bond and its dual responses

The State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science, Fudan University, Shanghai 200433, China

Corresponding author: Chen Guo-Song, guosong@fudan.edu.cn
Received Date: 7 April 2016
Revised Date: 3 May 2016
Accepted Date: 5 May 2016
Available Online: 21 December 2016

Figures(7)

In this paper, dynamic covalent bond has been employed to construct supra-amphiphile of carbohydrate for the first time. In neutral environment, the molecule was fabricated by reacting a hydrophobic building block bearing benzoic aldehyde with a hydrophilic building block bearing hydrazine to form a sugar-containing supra-amphiphile based on acylhydrazone bond. The obtained azobenzenegalactopyranoside (Azo-Gal) supra-amphiphile self-assembled to fibrillar structure in water, which showed dual responses to UV light and pH.
- Supra-amphiphile,
- Self-assembly,
- Dynamic covalent bond,
- Carbohydrate,
- Dual responses
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