Citation: Xiao Fang, Tang Chun-Ping, Ke Chang-Qiang, Yao Sheng, Ye Yang. Rearranged diterpenoids from the seeds of Caesalpinia sappan[J]. Chinese Chemical Letters, ;2016, 27(12): 1751-1754. doi: 10.1016/j.cclet.2016.04.022 shu

Rearranged diterpenoids from the seeds of Caesalpinia sappan

Xiao Fang ^a,b ,
Tang Chun-Ping ^a ,
Ke Chang-Qiang ^a ,
Yao Sheng ^a ,
Ye Yang ^a,c,,

a.
State Key Laboratory of Drug Research & Natural Products Chemistry Department, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
School of Life Science and Technology, ShanghaiTech University, Shanghai 201210, China

Corresponding author: Ye Yang, yye@simm.ac.cn
Received Date: 23 February 2016
Revised Date: 4 August 2016
Accepted Date: 19 April 2016
Available Online: 11 December 2016

Figures(3)

Two new rearranged diterpenoids, tomocinol C (1) and spirocaesalmin C (2) were isolated from the seeds of Caesalpinia sappan. Their structures were elucidated based on comprehensive analysis of spectroscopic data, and their absolute configurations were established by single crystal X-ray crystallography.
- Diterpenoid,
- Tomocinol C,
- Spirocaesalmin C,
- Caesalpinia sappan,
- Absolute configuration,
- X-ray crystallography
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