Citation: Fang Wang, Xue Li, Sheng Wang, Cheng-Peng Li, Huan Dong, Xiang Ma, Sung-Hoon Kim, De-Rong Cao. New π-conjugated cyanostilbene derivatives:Synthesis, characterization and aggregation-induced emission[J]. Chinese Chemical Letters, ;2016, 27(10): 1592-1596. doi: 10.1016/j.cclet.2016.04.020 shu

New π-conjugated cyanostilbene derivatives:Synthesis, characterization and aggregation-induced emission

Fang Wang ^a,b ,
Xue Li ^a,b ,
Sheng Wang ^a,b,, ,
Cheng-Peng Li ^b ,
Huan Dong ^c ,
Xiang Ma ^c,, ,
Sung-Hoon Kim ^d ,
De-Rong Cao ^a,,

a.
School of Chemistry and Chemical Engineering, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510641, China;
b.
Key Laboratory of Applied Chemistry and School of Chemistry and Chemical Engineering, Development Center for New Materials Engineering & Technology in Universities of Guangdong, Lingnan Normal University, Zhanjiang 524048, China;
c.
Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237, China
d.
Department of Advanced Organic Materials Science and Engineering, Kyungpook National University, Daegu 702-701, Republic of Korea

Corresponding author: Sheng Wang, dyesws@126.com Xiang Ma, maxiang@ecust.edu.cn De-Rong Cao, drcao@scut.edu.cn
Received Date: 15 March 2016
Revised Date: 17 April 2016
Accepted Date: 21 April 2016
Available Online: 11 October 2016

Figures(6)

Two novel π-conjugated cyanostilbene derivatives, FLU-CNPH and TPE-CNPH, were designed and synthesized by introducing the strong electron donor 1, 4-dihydropyrro^{[3, 2-b]}indole and AIE electron donor tetraphenylethylene (TPE) to the (30,50-bis(trifluoromethyl)-biphenyl-4-yl)-acetonitrile, respectively. Both of them were fully characterized and their AIE behaviors were investigated using fluorescence spectroscopy and FE-SEM images. Their optimized structures and frontier molecular orbitals were calculated with the DFT by using Materials Studio 7.0 software to study the relationship between the structure and properties.
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