Citation: Yang Jie, Ma Jian-Jun, Zhang Da-Min, Xue Teng, Guan Ye-Jun. Effect of organic moieties (phenyl, naphthalene, and biphenyl) in Zr-MIL-140 on the hydrogenation activity of Pd nanoparticles[J]. Chinese Chemical Letters, ;2016, 27(11): 1679-1682. doi: 10.1016/j.cclet.2016.04.015 shu

Effect of organic moieties (phenyl, naphthalene, and biphenyl) in Zr-MIL-140 on the hydrogenation activity of Pd nanoparticles

a.
School of Mathematics and Physics, Shanghai University of Electric Power, Shanghai 200090, China
b.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 200062, China

Corresponding author: Guan Ye-Jun, yjguan@chem.ecnu.edu.cn
Received Date: 23 February 2016
Revised Date: 23 March 2016
Accepted Date: 14 April 2016
Available Online: 23 November 2016

Figures(4)

MIL-140-type metal organic frameworks (isoreticular zirconium oxide MOFs) with different aromatic moieties (phenyl, naphthalene, and biphenyl) have been synthesized and employed as the supports of palladium nanoparticles (Pd NPs).The catalysts were characterized by XRD, BET, TEM and CO chemisorption.The results reveal that Pd NPs are homogeneously dispersed on all materials whereas different accessibility to CO is observed.The hydrogenation performance in C=C saturation with respect to the effect of the aromatic moiety is compared.The Pd/MIL-140A MOF with the highest hydrogenation activity among the three catalysts comprised of different aromatic rings points to a unique Pd-π interaction between Pd and frameworks consisting of mono-phenyl groups (C₆H₄).
- Metal-organic-framework,
- Palladium,
- Selective hydrogenation,
- Zirconium
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