Citation: Jie Li, Lin-Ping Qian, Li-Ya Hu, Bin Yue, He-Yong He. Low-temperature hydrogenation of maleic anhydride to succinic anhydride and γ-butyrolactone over pseudo-boehmite derived alumina supported metal (metal = Cu, Co and Ni) catalysts[J]. Chinese Chemical Letters, ;2016, 27(7): 1004-1008. doi: 10.1016/j.cclet.2016.03.021 shu

Low-temperature hydrogenation of maleic anhydride to succinic anhydride and γ-butyrolactone over pseudo-boehmite derived alumina supported metal (metal = Cu, Co and Ni) catalysts

Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China

Corresponding author: Bin Yue, yuebin@fudan.edu.cn He-Yong He, heyonghe@fudan.edu.cn
Received Date: 15 February 2016
Revised Date: 8 March 2016
Accepted Date: 11 March 2016
Available Online: 19 July 2016

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The pseudo-boehmite derived alumina supported metal (Cu, Co and Ni) catalysts prepared by the impregnation method were investigated in hydrogenation of maleic anhydride (MA) to succinic anhydride (SA) and γ-butyrolactone. The catalysts were characterized by ICP-AES, N₂ adsorption-desorption, XRD, H₂-TPR, CO-TPD, dissociative N₂O adsorption and TEM and the results showed that the alumina possessed mesoporous feature and the metal species were well dispersed on the support. Compared to Cu/Al₂O₃ and Co/Al₂O₃, Ni/Al₂O₃ exhibited higher catalytic activity in the MA hydrogenation with 92% selectivity to SA and nearly 100% conversion of MA at 140 ℃ under 0.5 MPa of H₂ with a weighted hourly space velocity of 2 h^-1 (MA). The stability of Ni/Al₂O₃ catalyst was also investigated.
- Maleic anhydride,
- Hydrogenation,
- Succinic anhydride,
- Nickel
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