Citation: Yong-Tao Zuo, Jun Peng, Gang Li, Li Liu, Zhi-Song Han, Gang Wang. The fabrication of hollow magnetite microspheres with a nearly 100% morphological yield and their applications in lithium ion batteries[J]. Chinese Chemical Letters, ;2016, 27(6): 887-890. doi: 10.1016/j.cclet.2016.02.003 shu

The fabrication of hollow magnetite microspheres with a nearly 100% morphological yield and their applications in lithium ion batteries

Yong-Tao Zuo ^a, ,
Jun Peng ^a ,
Gang Li ^a ,
Li Liu ^a ,
Zhi-Song Han ^a ,
Gang Wang ^a,b,c

a School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China;
b Engineering Research Center of Materials-Oriented Chemical Engineering of Xinjiang Production and Construction Corps, Shihezi 832003, China;
c Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous Region, Shihezi 832003, China

Received Date: 11 December 2015
Revised Date: 26 January 2016

Fund Project: This work was financially supported by Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT, No. IRT1161), Program of Science and Technology Innovation Team in Bingtuan (No. 2011CC001), and the National Natural Science Foundation of China (Nos. 21263021, U1303291).

Hollow Fe₃O₄ (H-Fe₃O₄) microspheres were fabricated through a facile one-step solvothermal synthesis, which was performed in an ethylene glycol (EG)-diethylene glycol (DEG) mixed solvent using polyethylene glycol (PEG) as the stabilizer. The addition of DEG increased the viscosity of the system, which caused the Fe₃O₄ primary crystal to aggregate slower and the morphological yield to approach nearly 100%. The as-prepared hollow Fe₃O₄ microspheres show promise for application in lithium ion battery anodes and showed a reversible specific capacity of 453.3 mAh g^-1 after 50 cycles at 100 mA g^-1. 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
- Hollow magnetite,
- Mixed solvent,
- Anode material,
- Lithium ion batteries
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