Citation: Bing-Tao Wang,  Fu-De Lu,  Feng Xu,  Yu-Zhan Li,  Michael R. Kessler. Synthesis of renewable isosorbide-based monomer and preparation of the corresponding thermosets[J]. Chinese Chemical Letters, ;2016, 27(6): 875-878. doi: 10.1016/j.cclet.2016.01.030 shu

Synthesis of renewable isosorbide-based monomer and preparation of the corresponding thermosets

  • Received Date: 20 October 2015
    Revised Date: 25 December 2015

    Fund Project: The authors gratefully acknowledge the National Natural Science Foundation of China (No. 51503181), Foundation of Educational Committee of Zhejiang Province of China (No. Y201225071), and Ningbo Natural Science Foundation of China (Nos. 2013A610135, 2015A610092, 2015A610100) for financial support.

  • Two kinds of difunctionalized isosorbide derivatives containing norbornene groups were designed and synthesized by a facile one-step reaction under mild conditions. 1 H NMR spectroscopy confirmed the chemical composition and differential scanning calorimetry (DSC) revealed the distinct curing behaviors between conventional petroleum-based dicyclopentadiene (DCPD) and synthesized renewable isosorbided-based monomer (ISN). In contrast to DCPD, ISN was low viscous liquid at room temperature and had even higher reactivity to perform ring-opening metathesis polymerization (ROMP) in the presence of Grubbs' catalyst. Due to the presence of flexible and elastic Si-C long chains, the cured poly(ISN) thermosets not only had good mechanical properties but also exhibited much higher storage modulus at the rubbery state in comparison with traditional poly(DCPD).
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    2. [2]

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    4. [4]

    5. [5]

    6. [6]

    7. [7]

    8. [8]

    9. [9]

    10. [10]

    11. [11]

    12. [12]

    13. [13]

    14. [14]

    15. [15]

    16. [16]

    17. [17]

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    1. [1]

      Zhen Li Min Yi Hua Zhang Yi Sheng Lai Si Xun Peng . Asymmetric synthesis of 3-butylphthalide using isomannide and isosorbide as chiral auxiliaries. Chinese Chemical Letters, 2007, 18(11): 1361-1363. doi: 10.1016/j.cclet.2007.09.038

    2. [2]

      Hao Ai Kai Xu Huan Liu Ming Cai Chen . Porous epoxy thermosets obtained by a reaction-induced process and their characterizations. Chinese Chemical Letters, 2008, 19(11): 1312-1314. doi: 10.1016/j.cclet.2008.09.026

    3. [3]

      Jian Qiang WANG Ming Hua XU Min ZHONG Guo Qiang LIN . Studies on the Diastereoselective Alkylation Reaction Employing Isomannide and Isosorbide as Chiral Auxiliaries. Chinese Chemical Letters, 1998, 9(4): 325-328.

    4. [4]

      Kong Liang Xie Yin He Su Chun Xiang Zhang . Synthesis and optical activity of isosorbide chiral derivative containing fluorocarbon group as chiral dopant in liquid crystal materials. Chinese Chemical Letters, 2011, 22(12): 1447-1450. doi: 10.1016/j.cclet.2011.07.021

    5. [5]

      Li JieWang YechengYu YanLi Qiaowei . Functionality proportion and corresponding stability study of multivariate metal-organic frameworks. Chinese Chemical Letters, 2018, 29(6): 837-841. doi: 10.1016/j.cclet.2017.12.026

    6. [6]

      Zhang XuLi Tao . Molecular-scale electronics: From device fabrication to functionality. Chinese Chemical Letters, 2017, 28(11): 2058-2064. doi: 10.1016/j.cclet.2017.09.008

    7. [7]

      Xiao Ming YU Shi Zhi CHEN Liang HUANG . Studies on the Total Synthesis of Hainanolide (Ⅵ)-The First Access to the Lactone Functionality. Chinese Chemical Letters, 2000, 11(4): 295-296.

    8. [8]

      Tzu-Chien FangHsing-Yang TsaiMing-Hui LuoChe-Wei ChangKew-Yu Chen . Excited-state charge coupled proton transfer reaction via the dipolar functionality of salicylideneaniline. Chinese Chemical Letters, 2013, 24(2): 145-148.

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