Citation: Reza Ojani, Parisa Hamidi, Jahan-Bakhsh Raoof. Efficient nonenzymatic hydrogen peroxide sensor in acidic media based on Prussian blue nanoparticles-modified poly (o-phenylenediamine)/glassy carbon electrode[J]. Chinese Chemical Letters, ;2016, 27(03): 481-486. doi: 10.1016/j.cclet.2015.12.030 shu

Efficient nonenzymatic hydrogen peroxide sensor in acidic media based on Prussian blue nanoparticles-modified poly (o-phenylenediamine)/glassy carbon electrode

1.
Electroanalytical Chemistry Research Laboratory, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran

Corresponding author: Reza Ojani,
Received Date: 27 May 2015
Available Online: 3 December 2015

The Prussian blue nanoparticles (PBNPs) were prepared by a self-assembly process, on a glassy carbon (GC) electrode modified with a poly(o-phenylenediamine) (PoPD) film. The stepwise fabrication process of PBNPs-modified PoPD/GCE was characterized by scanning electron microscopy (SEM) and electrochemical impedance spectroscopy. The prepared PBNPs showed an average size of 70 nm and a homogeneous distribution on the surface of modified electrodes. The PBNPs/PoPD/GCE showed adequate mechanical, electrochemical stability and good sensitivity in comparison with other PB based H₂O₂ sensors. The present modified electrode exhibited a linear response for H₂O₂ reduction over the concentration range of 1-58.22 μmol L^-1 with a detection limit of ca. 0.8 μmol L^-1 (S/N=3), and sensitivity of 3187.89 mA (mol L^-1)^-1 cm^-2 using the amperometric method. This sensor was employed for the H₂O₂ determination in real sample and also exhibited good interference resistance and selectivity.
- Self-assembly,
- Prussian blue nanoparticles,
- Hydrogen peroxide,
- Sensor
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