Citation: Dai Wu, Ying Gao, Wan-Guo Tian, Yun-Hui Li, Weiting Yang, Zhong-Ming Sun. Layered and three-dimensional uranyl-organic assemblies with 4,40-oxidiphthalic acid[J]. Chinese Chemical Letters, ;2016, 27(03): 325-329. doi: 10.1016/j.cclet.2015.12.016 shu

Layered and three-dimensional uranyl-organic assemblies with 4,40-oxidiphthalic acid

Dai Wu ^a ,
Ying Gao ^a,, ,
Wan-Guo Tian ^a ,
Yun-Hui Li ^a ,
Weiting Yang ^b,, ,
Zhong-Ming Sun ^b

a.
a. School of Chemistry and Environmental Engineering, Changchun University of Science & Technology, Changchun 130022, China;
b.
b. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: Ying Gao, Weiting Yang,
Received Date: 17 August 2015
Available Online: 29 September 2015
Fund Project: We thank the support of this work by National Natural Science Foundation of China (Nos.21571171, 21301168, U1407101) (Nos.21571171, 21301168, U1407101)Jilin Province Youth Foundation (No.20130522123JH). (No.20130522123JH)

Hydrothermal reactions of uranyl nitrate and 4,40-oxidiphthalic acid (H₄L) resulted in the formation of three new uranyl-organic framework materials, namely (NH₄)₂[(UO₂)₃(L)₂]·5H₂O (1), (NEt₄)[(UO₂)₃ (H₂O)(L)(HL)] (2) and (UO₂)₇(H₂O)₂(phen)₄(L)₂(HL)₂ (3) (NEt₄=tetraethylammonium, phen=1,10-phenanthroline). These three structures all comprise common uranyl pentagonal bipyramids. In 1, UO₇ polyhedra are linked by hexadentate ligands to form a 3D framework with 1D channels, in which are located NH₄⁺ ions and water molecules. While in 2, the organic ligands adopt pentadentate and hexadentate coordination modes, ligating UO₇ units to create a layered structure with channels filled by NEt₄⁺ ions. For 3, uranyl square bipyramids are also accommodated together with pentagonal bipyramids, which are linked by tetradentate carboxylate ligands to produce the layered assembly. Phen molecules also coordinate to the uranyl centers to build up the structure. Luminescent studies indicate that 2 and 3 exhibit the characteristic uranyl emission.
- Uranyl-organic assemblies,
- Carboxylates,
- Structures,
- Luminescence
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