Citation: Hai-Xia Pang, Yong-Hai Hui, Kui Fan, Xue-Jian Xing, Yang Wua, Jing-Hui Yang, Wei Shi, Zheng-Feng Xie. A catalysis study of mesoporous MCM-41 supported Schiff base and CuSO₄·5H₂O in a highly regioselective synthesis of 4-thiazolidinone derivatives from cyclocondensation of mercaptoacetic acid[J]. Chinese Chemical Letters, ;2016, 27(03): 335-339. doi: 10.1016/j.cclet.2015.10.029 shu

A catalysis study of mesoporous MCM-41 supported Schiff base and CuSO₄·5H₂O in a highly regioselective synthesis of 4-thiazolidinone derivatives from cyclocondensation of mercaptoacetic acid

a.
a. Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China;
b.
b. Oil & Gas Field Applied Chemistry Key Laboratory of Sichuan Province, School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China

Corresponding author: Yong-Hai Hui, Zheng-Feng Xie,
Received Date: 6 September 2015
Available Online: 19 October 2015
Fund Project:

Mesoporous MCM-41 supported Schiff base and CuSO₄·5H₂O shows high catalytic activity in the cyclocondensation of mercaptoacetic acid with imines (or aldehydes and amines) to afford pharmaceutically important thiazolidinone derivatives. The catalytic reactions involving twocomponents or three-components afforded the desired product in high yields (up to 98% and 99%). Moreover, the catalyst works well with respect to recyclability, giving the product in 85% and 83% yields after recycling six times.
- MCM-41,
- Schiff base,
- Cyclocondensation,
- Mercaptoacetic acid,
- Catalysis
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沈阳化工大学材料科学与工程学院沈阳 110142

A catalysis study of mesoporous MCM-41 supported Schiff base and CuSO4·5H2O in a highly regioselective synthesis of 4-thiazolidinone derivatives from cyclocondensation of mercaptoacetic acid

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通讯作者: 陈斌, bchen63@163.com

A catalysis study of mesoporous MCM-41 supported Schiff base and CuSO₄·5H₂O in a highly regioselective synthesis of 4-thiazolidinone derivatives from cyclocondensation of mercaptoacetic acid