Citation: Lin-Li Hu, Wen Xue, Jun Yin. Construction of a hetero pseudo[2]rota[2]catenane[J]. Chinese Chemical Letters, ;2016, 27(01): 155-158. doi: 10.1016/j.cclet.2015.09.010 shu

Construction of a hetero pseudo[2]rota[2]catenane

Lin-Li Hu ^a ,
Wen Xue ^b ,
Jun Yin ^b,,

1.
a College of Chemistry and Environmental Engineering, Yangtze University, Jingzhou 434023, China;
2.
b Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China

Corresponding author: Jun Yin,
Received Date: 20 July 2015
Available Online: 19 August 2015
Fund Project: The authors acknowledge financial support from National Natural Science Foundation of China(No. 21402057) (No. 21402057)

A novel ammonium template containing three ammonium sites was synthesized. Two ammoniums located on the linear component served as template for cucurbit[6]uril to form the CB-based pseudo[2]rotacane while another one located on the macrocyclic component played a role of template for clipping reaction. As a result of a "threading-followed-by-clipping" approach, a novel hetero pseudo[2]rota[2]catenane was successfully constructed.
- Templated synthesis,
- Threading-followed-by-clipping,
- Hetero pseudo[2]rota[2]catenane
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