Citation: Xiu-Yu Sun, Peng-Zhang Li, Bing Ai, Yue-Bo Wang. Surface modification of MCM-41 and its application in DNA adsorption[J]. Chinese Chemical Letters, ;2016, 27(01): 139-144. doi: 10.1016/j.cclet.2015.08.008 shu

Surface modification of MCM-41 and its application in DNA adsorption

1.
School of Chemical Engineering, Shandong University of Technology, Zibo 255000, China

Corresponding author: Yue-Bo Wang,
Received Date: 8 June 2015
Available Online: 15 July 2015
Fund Project: This work was supported by the National Natural Science Foundation of China(No. 21205070) (No. 21205070)

Three types of MCM-41 absorbents, namely, Al³⁺-MCM-41, La³⁺-MCM-41, and Zn²⁺-MCM-41, were prepared through amine grafting, phosphonate modification, and metal ion chelation and characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, and N₂ adsorption-desorption analysis. Results revealed that functionalized MCM-41 maintains the original structure of the molecular sieve and that the pore diameter and surface area are reduced compared with those of pure MCM-41. The adsorption behavior of DNA molecules on the surface of the modified molecular sieves was discussed according to the hard-soft acid-base(HSAB) principle. Experimental results showed that DNA purification could be effectively carried out on functionalized MCM-41 and that DNA is easily released by 3-4 mol L^-1 NaCl solution. This study could be used as a general platform for future work on DNA adsorption and enrichment.
- MCM-41,
- Surface modification,
- DNA,
- Adsorption
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沈阳化工大学材料科学与工程学院沈阳 110142