Citation: Zhi-Mei Luo, Yan-Guang Sun, Hui-Yong Liu. Electrochemical performance of a nano SnO₂-modified LiNi_1/3Co_1/3Mn_1/3O₂ cathode material[J]. Chinese Chemical Letters, ;2015, 26(11): 1403-1408. doi: 10.1016/j.cclet.2015.06.007 shu

Electrochemical performance of a nano SnO₂-modified LiNi_1/3Co_1/3Mn_1/3O₂ cathode material

1.
School of Chemical Engineering, Fuzhou University, Fuzhou 350116, China

Corresponding author: Hui-Yong Liu,
Received Date: 29 April 2015
Available Online: 8 June 2015

The nano SnO₂-modified LiNi_1/3Co_1/3Mn_1/3O₂ was successfully prepared by a carrier transfer method. The pristine and modified samples were characterized with various techniques such as XRD, SEM, XPS and EDS. The results showed that the SnO₂ particles did not enter the crystal structure of LiNi1/3Co1/ 3Mn1/3O₂, many nano SnO₂ particles were uniformly covered on the surface of LiNi_1/3Co_1/3Mn_1/3O₂ and the modified thin layer could inhibit the dissolution of transition metal oxides. The electrochemical tests indicated that the existence of nano SnO₂ could improve the discharge capacity and rate capability owing to the decreased interfacial polarization. The cycling stability was remarkably improved at room temperature and 55 ℃. The XRD patterns of the fresh NCM electrode and after 50 cycles proved that the structural change of NCM was not so effective on the capacity fade.
- Carrier transfer method
1. [1]
  [1] S.K. Hu, G.H. Cheng, M.Y. Cheng, et al., Cycle life improvement of ZrO₂-coated spherical LiNi_1/3Co_1/3Mn_1/3O₂ cathode material for lithium ion batteries, J. Power Sources 188 (2009) 564-569.
2. [2]
  [2] Y.L. Yao, H.C. Liu, G.C. Li, et al., Synthesis and electrochemical performance of phosphate-coated porous LiNi_1/3Co_1/3Mn_1/3O₂ cathode material for lithium ion batteries, Electrochim. Acta 113 (2013) 340-345.
3. [3]
  [3] K.C. Jiang, S. Xin, J.-S. Lee, et al., Improved kinetics of LiNi1/3Mn1/3Co1/3O₂ cathode material through reduced graphene oxide networks, Phys. Chem. Chem. Phys. 14 (2012) 2934-2939.
4. [4]
  [4] D.C. Li, Y. Kato, K. Kobayakawa, et al., Preparation and electrochemical characteristics of LiNi1/3Mn1/3Co1/3O₂ coated with metal oxides coating, J. Power Sources 160 (2006) 1342-1348.
5. [5]
  [5] H. Miyashiro, A. Yamanaka, M. Tabuchi, et al., Improvement of degradation at elevated temperature and at high state-of-charge storage by ZrO₂ coating on LiCoO₂, J. Electrochem. Soc. 153 (2006) A348-A353.
6. [6]
  [6] Z. Yang, X.H. Li, Z.X. Wang, et al., Surface modification of spherical LiNi_1/3Co_1/3Mn_1/3O₂ with A1₂O₃ using heterogeneous nucleation process, Trans. Nonferrous Met. Soc. China 17 (2007) 1319-1323.
7. [7]
  [7] L.A. Riley, S. Van Atta, A.S. Cavanagh, et al., Electrochemical effects of ALD surface modification on combustion synthesized LiNi1/3Mn1/3Co1/3O₂ as a layered-cathode material, J. Power Sources 196 (2011) 3317-3324.
8. [8]
  [8] X.Z. Liu, P. He, H.Q. Li, et al., Improvement of electrochemical properties of LiNi_1/3Co_1/3Mn_1/3O₂ by coating with V2O₅ layer, J. Alloys Compd. 552 (2013) 76-82.
9. [9]
  [9] N. Machida, J. Kashiwagi, M. Naito, et al., Electrochemical properties of all-solidstate batteries with ZrO₂ coated LiNi_1/3Co_1/3Mn_1/3O₂ as cathode materials, Solid State Ion. 225 (2012) 354-358.
10. [10]
  [10] F. Wu, M. Wang, Y.F. Su, et al., Effect of TiO₂-coating on the electrochemical performances of LiCo1/3Ni1/3Mn1/3O₂, J. Power Sources 191 (2009) 628-632.
11. [11]
  [11] M. Wang, F. Wu, Y.F. Su, et al., Modification of LiCo1/3 Ni1/3 Mn1/3 O₂ cathode material by CeO₂-coating, Sci. China Ser. E: Technol. Sci. 52 (2009) 2737- 2741.
12. [12]
  [12] F. Wu, M. Wang, Y.F. Su, et al., Surface of LiCo1/3Ni1/3Mn1/3O₂ modified by CeO₂- coating, Electrochim. Acta 54 (2009) 6803-6807.
13. [13]
  [13] K. Yang, L.Z. Fan, J. Guo, et al., Surface of LiCo1/3Ni1/3Mn1/3O₂ modified by CeO₂- coating, Electrochim. Acta 63 (2012) 363-368.
14. [14]
  [14] J. Cho, C.-S. Kim, S.-I. Yoo, Improvement of structural stability of LiCoO₂ cathode during electrochemical cycling by sol-gel coating of SnO₂, Electrochem. Solid- State Lett. 3 (2000) 362-365.
15. [15]
  [15] D. Ziolkowska, K.P. Korona, B. Hamankiewicz, et al., The role of SnO₂ surface coating on the electrochemical performance of LiFePO₄ cathode materials, Electrochim. Acta 108 (2013) 532-539.
16. [16]
  [16] L. Wang, J.S. Zhao, S.H. Guo, et al., Investigation of SnO₂-modified LiMn₂O₄ composite as cathode material for lithium-ion batteries, Int. J. Electrochem. Sci. 5 (2010) 1113-1126.
17. [17]
  [17] C.E. Lia, W.Y. Ye, H.Y. Liu, et al., Preparation of TiO₂-coated LiMn₂O₄ by carrier transfer method, Ionics 15 (2009) 389-392.
18. [18]
  [18] H.-J. Ahn, H.-C. Choi, K.-W. Park, et al., Investigation of the structural and electrochemical properties of size-controlled SnO₂ nanoparticles, J. Phys. Chem. B 108 (2004) 9815-9820.
19. [19]
  [19] X.Z. Liu, H.Q. Li, E. Yoo, et al., Fabrication of FePO₄ layer coated LiNi_1/3Co_1/3Mn_1/3O₂: towards high-performance cathode materials for lithium ion batteries, Electrochim. Acta 83 (2012) 253-258.
20. [20]
  [20] H. Li, Z.X. Wang, L.Q. Chen, et al., Research on advanced materials for Li-ion batteries, Adv. Mater. 21 (2009) 4593-4607.
21. [21]
  [21] K.M. Shaju, G.V. Subba Rao, B.V.R. Chowdari, Performance of layered Li(Ni1/3Co1/3Mn1/3)O₂ as cathode for Li-ion batteries, Electrochim. Acta 48 (2002) 145-151.
22. [22]
  [22] C.V. Rao, A.L.M. Reddy, Y. Ishikawa, et al., LiNi_1/3Co_1/3Mn_1/3O₂-graphene composite as a promising cathode for lithium-ion batteries, ACS Appl. Mater. Interfaces 3 (2011) 2966-2972.
23. [23]
  [23] C.X. Huang, D.D. Chen, Y.Y. Huang, et al., Sol-gel synthesis of Li₃V₂(PO₄)₃/C cathode materials with high electrical conductivity, Electrochim. Acta 100 (2013) 1-9.
24. [24]
  [24] H.H. Zheng, Q.N. Sun, G. Liu, et al., Correlation between dissolution behavior and electrochemical cycling performance for LiNi_1/3Co_1/3Mn_1/3O₂-based cells, J. Power Sources 207 (2012) 134-140.
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Electrochemical performance of a nano SnO2-modified LiNi1/3Co1/3Mn1/3O2 cathode material

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Electrochemical performance of a nano SnO₂-modified LiNi_1/3Co_1/3Mn_1/3O₂ cathode material