Citation: Shuang-Lei Yang, Bang-Hong Zhou, Mei Lei, Lan-Ping Huang, Jun Pan, Wei Wu, Hong-Bo Zhang. Sub-100 nm hollow SnO₂@C nanoparticles as anode material for lithium ion batteries and significantly enhanced cycle performances[J]. Chinese Chemical Letters, ;2015, 26(10): 1293-1297. doi: 10.1016/j.cclet.2015.05.051 shu

Sub-100 nm hollow SnO₂@C nanoparticles as anode material for lithium ion batteries and significantly enhanced cycle performances

Shuang-Lei Yang ^1,2 ,
Bang-Hong Zhou ¹ ,
Mei Lei ² ,
Lan-Ping Huang ¹ ,
Jun Pan ¹ ,
Wei Wu ^2,3,, ,
Hong-Bo Zhang ^1,,

1.
1 State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China;
2.
2 Laboratory of Printable Functional Nanomaterials and Printing Electronics, School of Printing and Packaging, Wuhan University, Wuhan 430072, China;
3.
3 Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR 999077, China

Corresponding author: Wei Wu, Hong-Bo Zhang,
Received Date: 25 March 2015
Available Online: 19 May 2015
Fund Project: We greatly acknowledge partial financial support by the Program for the NSFC (Nos. 51302325, 51201115, 51471121) (Nos. 51302325, 51201115, 51471121) New Century Excellent Talents in University (No. NCET-12-0553) (No. NCET-12-0553) Program for Shenghua Overseas Talent (No. 1681-7607030005) from Central South University, Hubei Provincial Natural Science Foundation (No. 2014CFB261) (No. 1681-7607030005)Wuhan University. (No. CSUZC2014032)

Rational designing and controlling of nanostructures is a key factor in realizing appropriate properties required for the high-performance energy fields. In the present study, hollow SnO₂@C nanoparticles (NPs) with a mean size of 50 nm have been synthesized in large-scale via a facile hydrothermal approach. The morphology and composition of as-obtained products were studied by various characterized techniques. As an anode material for lithium ion batteries (LIBs), the as-prepared hollow SnO₂@C NPs exhibit significant improvement in cycle performances. The discharge capacity of lithium battery is as high as 370 mAh g^-1, and the current density is 3910 mA g^-1(5 C) after 573 cycles. Furthermore, the capacity recovers up to 1100 mAh g^-1 at the rate performances in which the current density is recovered to 156.4 mA g^-1(0.2 C). Undoubtedly, sub-100 nm SnO₂@C NPs provide significant improvement to the electrochemical performance of LIBs as superior-anode nanomaterials, and this carbon coating strategy can pave the way for developing high-performance LIBs.
- Tin oxide nanoparticles,
- Carbon coating,
- Lithium ion batteries,
- Anode nanomaterials,
- Size-controllable synthesis
1. [1]
  [1] J.R. Dahn, T. Zheng, Y.H. Liu, J.S. Xue, Mechanisms for lithium insertion in carbonaceous materials, Science 270(1995) 590-593.
2. [2]
  [2] J.M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries, Nature 414(2001) 359-367.
3. [3]
  [3] X.W. Lou, J.S. Chen, P. Chen, L.A. Archer, One-pot synthesis of carbon-coated SnO₂ nanocolloids with improved reversible lithium storage properties, Chem. Mater. 21(2009) 2868-2874.
4. [4]
  [4] M.G. Kim, J. Cho, Reversible and high-capacity nanostructured electrode materials for Li-ion batteries, Adv. Funct. Mater. 19(2009) 1497-1514.
5. [5]
  [5] J.X. Li, Y. Zhao, N. Wang, L.H. Guan, A high performance carrier for SnO₂ nanoparticles used in lithium ion battery, Chem. Commun. 47(2011) 5238-5240.
6. [6]
  [6] J.M. Ma, J. Zhang, S.R. Wang, et al., Superior gas-sensing and lithium-storage performance SnO₂ nanocrystals synthesized by hydrothermal method, CrystEng-Comm 13(2011) 6077-6081.
7. [7]
  [7] G.F. Xia, N. Li, D.Y. Li, et al., Molten-salt decomposition synthesis of SnO₂ nanoparticles as anode materials for lithium ion batteries, Mater. Lett. 65(2011) 3377-3379.
8. [8]
  [8] J.J. Cai, Z.S. Li, S. Yao, et al., Close-packed SnO₂ nanocrystals anchored on amorphous silica as a stable anode material for lithium-ion battery, Electrochim. Acta 74(2012) 182-188.
9. [9]
  [9] K. Ui, S. Kawamura, N. Kumagai, Fabrication of binder-free SnO₂ nanoparticle electrode for lithium secondary batteries by electrophoretic deposition method, Electrochim. Acta 76(2012) 383-388.
10. [10]
  [10] W.S. Kim, Y. Hwa, J.H. Jeun, H.J. Sohn, S.H. Hong, Synthesis of SnO₂ nano hollow spheres and their size effects in lithium ion battery anode application, J. Power Sources 225(2013) 108-112.
11. [11]
  [11] W. Wei, L.X. Song, L. Guo, SnO₂ hollow nanospheres assembled by single layer nanocrystals as anode material for high performance Li ion batteries, Chin. Chem. Lett. 26(2015) 124-128.
12. [12]
  [12] H. Kim, J. Cho, Hard templating synthesis of mesoporous and nanowire SnO₂ lithium battery anode materials, J. Mater. Chem. 18(2008) 771-775.
13. [13]
  [13] K. Shiva, S. Asokan, A.J. Bhattacharyya, Improved lithium cyclability and storage in a multi-sized pore ("differential spacers") mesoporous SnO₂, Nanoscale 3(2011) 1501-1503.
14. [14]
  [14] S.J. Ding, X.W.D. Lou, SnO₂ nanosheet hollow spheres with improved lithium storage capabilities, Nanoscale 3(2011) 3586-3588.
15. [15]
  [15] Z.Y. Wang, D.Y. Luan, F.Y.C. Boey, X.W. Lou, Fast formation of SnO₂ nanoboxes with enhanced lithium storage capability, J. Am. Chem. Soc. 133(2011) 4738-4741.
16. [16]
  [16] H.B. Wu, J.S. Chen, X.W. Lou, H.H. Hng, Synthesis of SnO₂ hierarchical structures assembled from nanosheets and their lithium storage properties, J. Phys. Chem. C 115(2011) 24605-24610.
17. [17]
  [17] C. Wang, Y. Zhou, M. Ge, et al., Large-scale synthesis of SnO₂ nanosheets with high lithium storage capacity, J. Am. Chem. Soc. 132(2009) 46-47.
18. [18]
  [18] P. Wu, M.Y. Du, H. Zhang, C.X. Zhai, D.R. Yang, Self-templating synthesis of SnO₂-carbon hybrid hollow spheres for superior reversible lithium ion storage, ACS Appl. Mater. Interfaces 3(2011) 1946-1952.
19. [19]
  [19] X.W. Lou, Y. Wang, C. Yuan, J.Y. Lee, L.A. Archer, Template-free synthesis of SnO₂ hollow nanostructures with high lithium storage capacity, Adv. Mater. 18(2006) 2325-2329.
20. [20]
  [20] X.W. Lou, D. Deng, J.Y. Lee, L.A. Archer, Preparation of SnO₂/carbon composite hollow spheres and their lithium storage properties, Chem. Mater. 20(2008) 6562-6566.
21. [21]
  [21] W.M. Zhang, X.L. Wu, J.S. Hu, Y.G. Guo, L.J. Wan, Carbon coated Fe₃O₄ nanospindles as a superior anode material for lithium-ion batteries, Adv. Funct. Mater. 18(2008) 3941-3946.
22. [22]
  [22] H. Li, H. Zhou, Enhancing the performances of Li-ion batteries by carbon-coating:present and future, Chem. Commun. 48(2012) 1201-1217.
23. [23]
  [23] J. Liu, W. Li, A. Manthiram, Dense core-shell structured SnO₂/C composites as high performance anodes for lithium ion batteries, Chem. Commun. 46(2010) 1437-1439.
24. [24]
  [24] Y. Chen, Q.Z. Huang, J. Wang, Q. Wang, J.M. Xue, Synthesis of monodispersed SnO₂@C composite hollow spheres for lithium ion battery anode applications, J. Mater. Chem. 21(2011) 17448-17453.
25. [25]
  [25] S.M. Paek, E. Yoo, I. Honma, Enhanced cyclic performance and lithium storage capacity of SnO₂/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure, Nano Lett. 9(2008) 72-75.
26. [26]
  [26] L. Wang, D. Wang, H.Z. Dong, F.X. Zhang, J. Jin, Interface chemistry engineering for stable cycling of reduced GO/SnO₂ nanocomposites for lithium ion battery, Nano Lett. 13(2013) 1711-1716.
27. [27]
  [27] H. Park, T. Song, H. Han, et al., SnO₂ encapsulated TiO₂ hollow nanofibers as anode material for lithium ion batteries, Electrochem. Commun. 22(2012) 81-84.
28. [28]
  [28] N. Feng, L. Qiao, D.K. Hu, X.L. Sun, P. Wang, D.Y. He, Synthesis, characterization, and lithium-storage of ZnO-SnO₂ hierarchical architectures, RSC Adv. 3(2013) 7758-7764.
29. [29]
  [29] W. Wu, S.F. Zhang, J. Zhou, et al., Controlled synthesis of monodisperse sub-100 nm hollow SnO₂ nanospheres:a template- and surfactant-free solutionphase route, the growth mechanism, optical properties, and application as a photocatalyst, Chem. Eur. J. 17(2011) 9708-9719.
30. [30]
  [30] S.Y. Liu, Y.H. Ma, S.P. Armes, C. Perruchot, J.F. Watts, Direct verification of the core-shell structure of shell cross-linked micelles in the solid state using X-ray photoelectron spectroscopy, Langmuir 18(2002) 7780-7784.
31. [31]
  [31] Q.Y. Tian, W. Wu, L.L. Sun, et al., Tube-like ternary α-Fe₂O₃@SnO₂@Cu₂O sandwich heterostructures:synthesis and enhanced photocatalytic properties, ACS Appl. Mater. Interfaces 6(2014) 13088-13097.
32. [32]
  [32] W. Wu, Q.G. He, H. Chen, J.X. Tang, L.B. Nie, Sonochemical synthesis, structure and magnetic properties of air-stable Fe₃O₄/Au nanoparticles, Nanotechnology 18(2007) 145609.
33. [33]
  [33] J.J. Chen, K. Yano, Highly monodispersed tin oxide/mesoporous starbust carbon composite as high-performance Li-ion battery anode, ACS Appl. Mater. Interfaces 5(2013) 7682-7687.
34. [34]
  [34] X.F. Li, X.B. Meng, J. Liu, et al., Tin oxide with controlled morphology and crystallinity by atomic layer deposition onto graphene nanosheets for enhanced lithium storage, Adv. Funct. Mater. 22(2012) 1647-1654.
35. [35]
  [35] J.P. Liu, Y.Y. Li, X.T. Huang, et al., Direct growth of SnO₂ nanorod array electrodes for lithium-ion batteries, J. Mater. Chem. 19(2009) 1859-1864.
36. [36]
  [36] X.W. Guo, X.P. Fang, Y. Sun, et al., Lithium storage in carbon-coated SnO₂ by conversion reaction, J. Power Sources 226(2013) 75-81.
37. [37]
  [37] M. He, L.X. Yuan, X.L. Hu, et al., A SnO₂@carbon nanocluster anode material with superior cyclability and rate capability for lithium-ion batteries, Nanoscale 5(2013) 3298-3305.
38. [38]
  [38] M. Zhang, Y.W. Li, E. Uchaker, et al., Homogenous incorporation of SnO₂ nanoparticles in carbon cryogels via the thermal decomposition of stannous sulfate and their enhanced lithium-ion intercalation properties, Nano Energy 2(2013) 769-778.
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Sub-100 nm hollow SnO2@C nanoparticles as anode material for lithium ion batteries and significantly enhanced cycle performances

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通讯作者: 陈斌, bchen63@163.com

Sub-100 nm hollow SnO₂@C nanoparticles as anode material for lithium ion batteries and significantly enhanced cycle performances