Citation:
Ya-Wen Zhou, Meng-Yuan Wang, Wei Zhou, Fu Han, Bao-Cai Xu. Dielectric relaxation behavior of SDS/β-CD organized self-assembly in dilute aqueous solution[J]. Chinese Chemical Letters,
;2015, 26(7): 905-908.
doi:
10.1016/j.cclet.2015.05.014
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Dielectric relaxation behavior of SDS/β-CD self-organized with mass concentrations from 1% to 7% was investigated. The phase microstructure of SDS/β-CD aqueous solution was confirmed by analyzing the dielectric parameters. The dielectric relaxation behavior was attributed to the interfacial polarization between vesicle and medium, and the relaxation distribution parameter can indicate the shape transition from vesicles to microtubules with increasing concentration. Dielectric relaxation provided a new method to study surfactant organized self-assembly.
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Keywords:
- Dielectric relaxation,
- Microstructure,
- Vesicle,
- Micro-tube
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[1]
[1] A.B. Dorrego, L. García-Río, P. Hervé s, Micellization versus cyclodextrin–surfactant complexation, Angew. Chem. Int. Ed. 39 (2000) 2945–2948.
-
[2]
[2] A.J. Valente, O. Söderman, The formation of host–guest complexes between surfactants and cyclodextrins, Adv. Colloid Interface Sci. 205 (2014) 156–176.
-
[3]
[3] L. Jiang, Y. Yan, J. Huang, Selectivity and stoichiometry boosting of β-cyclodextrin in cationic/anionic surfactant systems: when host–guest equilibrium meets biased aggregation equilibrium, J. Phys. Chem. B 114 (2010) 2165–2174.
-
[4]
[4] Y. Yan, L. Jiang, J. Huang, Unveil the potential function of CD in surfactant systems, Phys. Chem. Chem. Phys. 13 (2011) 9074–9082.
-
[5]
[5] L.X. Jiang, M. Deng, Y. Wang, Special effect of β-cyclodextrin on the aggregation behavior of mixed cationic/anionic surfactant systems, J. Phys. Chem. B 113 (2009) 7498–7504.
-
[6]
[6] L.X. Jiang, Y. Yan, J. Huang, Selectivity and stoichiometry boosting of β-cyclodextrin in cationic/anionic surfactant systems: when host–guest equilibrium meets biased aggregation equilibrium, J. Phys. Chem. B 114 (2010) 2165–2174.
-
[7]
[7] L.X. Jiang, Y. Yan, J. Huang, Zwitterionic surfactant/cyclodextrin hydrogel: microtubes and multiple responses, Soft Matter 7 (2011) 10417–10423.
-
[8]
[8] L.X. Jiang, Y. Yan, J. Huang, Versatility of cyclodextrins in self-assembly systems of amphiphiles, Adv. Colloid Interface Sci. 169 (2011) 13–25.
-
[9]
[9] L. Zheng, M. Suzuki, T. Inoue, Aqueous phase behavior of hexaethylene glycol dodecyl ether studied by differential scanning calorimetry, Fourier transform infrared spectroscopy, and 13C NMR spectroscopy, Langmuir 18 (2002) 9204–9210.
-
[10]
[10] A. Tonegawa, K. Ohno, H. Matsuura, A combined Raman and deuterium NMR spectroscopic study on the molecular and phase structure of a nonionic surfactant c12e5-water system, J. Phys. Chem. B 106 (2002) 13211–13223.
-
[11]
[11] H. Walderhaug, K.D. Knudsen, Microstructures in aqueous solutions of a polyoxyethylene trisiloxane surfactant and a co-surfactant studied by SANS and NMR self-diffusion, Langmuir 24 (2008) 10637–10645.
-
[12]
[12] D.J.F. Taylor, R.K. Thomas, J. Penfold, Polymer/surfactant interactions at the air/water interface, Adv. Colloid Interface Sci. 132 (2007) 69–110.
-
[13]
[13] P. Gianni, L. Bernazzani, R. Carosi, Micellization of lithium perfluoroheptanoate and its aggregation on poly (ethylene glycol) oligomers in water, Langmuir 23 (2007) 8752–8759.
-
[14]
[14] L.X. Jiang, Y. Peng, Y. Yan, Aqueous self-assembly of SDS@2β-CD complexes: lamellae and vesicles, Soft Matter 7 (2011) 1726–1731.
-
[15]
[15] L.X. Jiang, Y. Peng, Y. Yan, Annular Ring microtubes formed by SDS@2β-CD complexes in aqueous solution, Soft Matter 6 (2010) 1731–1736.
-
[16]
[16] L.K. Yang, K.S. Zhao, J.X. Xiao, Study of tetrabutylammonium perfluorooctanoate aqueous solutions with two cloud points by dielectric relaxation spectroscopy, Langmuir 22 (2006) 8655–8662.
-
[17]
[17] L. Yang, K. Zhao, Dielectric model and theoretical analysis of cationic reverse micellar solutions in CTAB/isooctane/n-hexanol/water systems, Langmuir 23 (2007) 8732–8739.
-
[18]
[18] W. Schrader, S. Halstenberg, R. Behrends, U. Kaatze, Critical slowing in lipid bilayers, J. Phys. Chem. B 107 (2003) 14457–14463.
-
[19]
[19] Y.W. Zhou, W. Zhou, F. Han, Dielectric analysis on phase transition and micelle shape of polyoxyethylene trisiloxane surfactant in dilute aqueous solution, Chin. Chem. Lett. 22 (2011) 745–748.
-
[20]
[20] Y. Lian, K. Zhao, Study of micelles and microemulsions formed in a hydrophobic ionic liquid by a dielectric spectroscopy method. I. Interaction and percolation, Soft Matter 7 (2011) 8828–8837.
-
[21]
[21] L. Ma, K. Zhao, Dielectric relaxation spectroscopy for the binary system of 1-butyl- 3-methylimidazolium hexafluorophosphate and ethanol: interactions and micro phase behavior, RSC Adv. 2 (2012) 10007–10014.
-
[22]
[22] W.R. Redwood, S. Takashima, H.P. Schwan, T.E. Thompson, Dielectric studies on homogeneous phosphatidylcholine vesicles, Biochim. Biophys. Acta 255 (1972) 557–566.
-
[23]
[23] R. Barchini, H.P. Van Leeuwen, J. Lyklema, Electrodynamics of liposome dispersions, Langmuir 16 (2000) 8238–8247.
-
[24]
[24] K. Asami, Dielectric relaxation in a water-oil-triton X-100 microemulsion near phase inversion, Langmuir 21 (2005) 9032–9037.
-
[25]
[25] K. Asami, Characterization of heterogeneous systems, Prog. Polym. Sci. 27 (2002) 1617–1659.
-
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