Citation: Jing Lai, Xian-Sheng Ke, Juan Tang, Jun-Long Zhang. Tris(Znsalen) cryptand minimizes Znsalen aggregation arising from intermolecular Zn···O interaction[J]. Chinese Chemical Letters, ;2015, 26(8): 937-941. doi: 10.1016/j.cclet.2015.04.023 shu

Tris(Znsalen) cryptand minimizes Znsalen aggregation arising from intermolecular Zn···O interaction

1.
a College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China;
2.
b Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: Jun-Long Zhang,
Received Date: 5 February 2015
Available Online: 1 April 2015
Fund Project: This project was supported by the National Scientific Foundation of China (No. 20971007) (No. 20971007)National Key Basic Research Support Foundation of China (NKBRSFC) (Nos. 2013CB933402, 2015CB856300). (NKBRSFC)

Exploring the factors to control Znsalen aggregation is of importance to design functional materials in catalysis, optical materials and biological imaging. In this work, we synthesized and characterized four cryptand type triZnsalen complexes and found that cryptand structure could efficiently minimize intermolecular Zn···O interaction. More importantly, encapsulated by PLGA nanoparticles, cryptand triZnsalen 1 displayed visible intracellular fluorescence whereas monomeric Znsalen 5 could not. These results provide a new access to design new luminescent materials with the potential application in optics and biological studies.
- Coordination chemistry,
- ZnSalen,
- Cryptand,
- Aggregation
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