Citation: Dan Tian, Xiao-Jing Liu, Rong-Ying Chen, Ying-Hui Zhang. Syntheses, structures, luminescent and magnetic properties of two coordination polymers based on a fl exible multidentate carboxylate ligand[J]. Chinese Chemical Letters, ;2015, 26(5): 499-503. doi: 10.1016/j.cclet.2015.01.019 shu

Syntheses, structures, luminescent and magnetic properties of two coordination polymers based on a fl exible multidentate carboxylate ligand

1.
Department of Chemistry and TKL of Metal- and Molecule-Based Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

Corresponding author: Ying-Hui Zhang,
Received Date: 2 December 2014
Available Online: 9 January 2015
Fund Project: This work was supported by the 973 Program of China (No. 2014CB845600) (No. 2014CB845600)

Two coordination polymers, {[Cu₃(tci)₂(DMAc)₃]·6DMAc·2H₂O}_n (1) and {[Cu₃(tci)₂(tpt)₂(H₂O)₂]·2DMAc·2H₂O}_n (2) (H₃tci = tris(2-carboxyethyl)isocyanurate, tpt = 2,4,6-tris(4-pyridyl)-1,3,5-triazine, DMAc = N,N-dimethylacetamide), have been constructed under solvothermal conditions. Both polymers were structurally characterized by single crystal X-ray diffraction, elemental analyses, IR spectra, thermogravimetric (TG) analyses and powder X-ray diffraction (RXPD). 1 shows a (3,4)-connected 2D layer structure comprising Cu₂(CO₂)₄ paddle-wheel units, which are further bridged by C-H…O interactions to give a 3D supramolecular network. The introduction of tpt produces different framework for 2 that comprises a dinuclear and a mononuclear Cu(II) building units, which are further bridged together by tci^3- and tpt ligands to give a 4-connected 2D topological net. Adjacent 2D layers are packed together via C-H…O interactions and π…π stacking interactions to form a 3D supramolecular structure. In addition, the luminescent properties and the solid-state UV-vis spectra of 1 and 2 were explored. Furthermore, antiferromagnetic exchange interactions were unveiled in the Cu₂(COO)₄ units of 1.
- Coordination polymers,
- X-ray crystallography,
- Copper,
- Magnetic properties,
- Luminescence
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