Citation: Yu Feng, Chuan-Gang Hu, Mei-Ling Qi, Ruo-Nong Fu, Liang-Ti Qu. Separation performance of graphene oxide as stationary phase for capillary gas chromatography[J]. Chinese Chemical Letters, ;2015, 26(1): 47-49. doi: 10.1016/j.cclet.2014.10.001 shu

Separation performance of graphene oxide as stationary phase for capillary gas chromatography

1.
Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials and School of Chemistry, Beijing Institute of Technology, Beijing 100081, China

Corresponding author: Mei-Ling Qi, Liang-Ti Qu,
Received Date: 1 August 2014
Available Online: 24 September 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 21075010, 21174019) (Nos. 21075010, 21174019)

Graphene oxide (GO) has attracted extensive attention due to its unique properties and potential applications. Here, we report the investigation of GO nanosheets as a stationary phase for capillary gas chromatographic (GC) separations. The GO column, fabricated by a new one-step coating approach, showed average McReynolds constants of 308, suggesting the mediumpolar nature of the GC stationary phase. The GO stationary phase achieves good separation for analytes of different types with good peak shapes, especially for H-bonding analytes, such as alcohols and amines. The different retention behaviors of GO stationary phase from the conventional stationary phase may originate from its multiple interactions with analytes, involving H-bonding, dipole-dipole, π-π stacking and dispersive interactions. Moreover, GO column showed good separation reproducibility with relative standard deviation (RSD%) less than 0.24% (n = 5) on retention times of analytes.
- Graphene oxide nanosheets,
- Stationary phase,
- Separation performance,
- Capillary gas chromatography
1. [1]
  [1] D.R. Dreyer, S. Park, C.W. Bielawski, R.S. Ruoff, The chemistry of graphene oxide, Chem. Soc. Rev. 39 (2010) 228-240.
2. [2]
  [2] Y. Zhu, S. Murali, W. Cai, et al., Graphene and graphene oxide: synthesis, properties and applications, Adv. Mater. 22 (2010) 3906-3924.
3. [3]
  [3] J.I. Paredes, S. Villar-Rodil, A. Martínez-Alonso, J.M.D. Tascón, Graphene oxide dispersions in organic solvents, Langmuir 24 (2008) 10560-10564.
4. [4]
  [4] J. Kim, L.J. Cote, J.X. Huang, Two dimensional soft material: new faces of graphene oxide, Acc. Chem. Res. 45 (2012) 1356-1364.
5. [5]
  [5] C. Chung, Y.K. Kim, D. Shin, et al., Biomedical applications of graphene and graphene oxide, Acc. Chem. Res. 46 (2013) 2211-2224.
6. [6]
  [6] E. Guihen, Nanoparticles in modern separation science, Trends Anal. Chem. 46 (2013) 1-14.
7. [7]
  [7] X. Liu, X.L. Liu, M. Li, L.P. Guo, L. Yang, Application of graphene as the stationary phase for open-tubular capillary electrochromatography, J. Chromatogr. A 1277 (2013) 93-97.
8. [8]
  [8] Q.S. Qu, C.H. Gu, Z.L. Gu, et al., Layer-by-layer assembly of polyelectrolyte and graphene oxide for open-tubular capillary electrochromatography, J. Chromatogr. A 1282 (2013) 95-101.
9. [9]
  [9] Y.Y. Xu, X.Y. Niu, Y.L. Dong, et al., Preparation and characterization of open-tubular capillary column modified with graphene oxide nanosheets for the separation of small organic molecules, J. Chromatogr. A 1284 (2013) 180-187.
10. [10]
  [10] M.M. Wang, X.P. Yan, Fabrication of graphene oxide nanosheets incorporated monolithic column via one-step room temperature polymerization for capillary electrochromatography, Anal. Chem. 84 (2012) 39-44.
11. [11]
  [11] Q.S. Qu, C.H. Gu, X.Y. Hu, Capillary coated with graphene and graphene oxide sheets as stationary phase for capillary electrochromatography and capillary liquid chromatography, Anal. Chem. 84 (2012) 8880-8890.
12. [12]
  [12] Q.S. Qu, Y.Q. Shen, C.H. Gu, et al., Capillary column coated with graphene oxide as stationary phase for gas chromatography, Anal. Chim. Acta 757 (2012) 83-87.
13. [13]
  [13] C.G. Hu, H.H. Cheng, Y. Zhao, et al., Newly designed complex ternary Pt/PdCu nanoboxes anchored on three-dimensional graphene framework for highly efficient ethanol oxidation, Adv. Mater. 24 (2012) 5493-5498.
14. [14]
  [14] L.J. Cote, F. Kim, J.X. Huang, Langmuir-Blodgett assembly of graphite oxide single layers, J. Am. Chem. Soc. 131 (2009) 1043-1049.
15. [15]
  [15] W.S. Hummers, R.E. Offeman, Preparation of graphitic oxide, J. Am. Chem. Soc. 80 (1958) 1339.
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沈阳化工大学材料科学与工程学院沈阳 110142