Citation:
Wei Wang, Ye Yuan, Fu-Xing Sun, Guang-Shan Zhu. Targeted synthesis of novel porous aromatic frameworks with selective separation of CO2/CH4 and CO2/N2[J]. Chinese Chemical Letters,
;2014, 25(11): 1407-1410.
doi:
10.1016/j.cclet.2014.08.002
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Novel porous aromatic frameworks (PAF-53 and PAF-54) have been obtained by the polymerization of amino compound (p-phenylenediamine and melamine) and cyanuric chloride. They display a certain amount of CO2 adsorption capacity and highly selective separation of CO2/CH4 and CO2/N2 as 18.1 and 83 by Henry Law respectively. They may be applied as ideal adsorbents to separate and capture CO2.
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