Citation: Wen-Jia Cai, Lin-Ping Qian, Bin Yue, He-Yong He. Rh doping effect on coking resistance of Ni/SBA-15 catalysts in dry reforming of methane[J]. Chinese Chemical Letters, ;2014, 25(11): 1411-1415. doi: 10.1016/j.cclet.2014.06.016 shu

Rh doping effect on coking resistance of Ni/SBA-15 catalysts in dry reforming of methane

1.
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China

Corresponding author: Bin Yue, He-Yong He,
Received Date: 9 May 2014
Available Online: 11 June 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (21173050, 21371035). (21173050, 21371035)

A series of SBA-15 supported bimetallic Rh-Ni catalysts with different weight ratio of Rh/Ni in the range of 0-0.04 were prepared for carbon dioxide reforming of methane. The doping effect of Rh on catalytic activity as well as carbon accumulation and removal over the catalysts was studied. The characterization results indicated that the addition of a small amount of Rh promoted the reducibility of Ni particles and decreased the Ni particle size. During the dry reforming reaction, the carbon deposition was originated from CH₄ decomposition and CO disproportionation. The Rh-Ni catalyst with smallmetallic particle size inhibited the carbon formation and exhibited high efficiency in the removal of coke. In comparison with bare Ni-based catalyst, the Rh-Ni bimetallic catalysts showed high activity and stability in the dry reforming of methane.
- Methane reforming,
- Carbon dioxide,
- Rh-Ni/SBA-15,
- Carbon deposition
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